优化盐类 [V10O28]6- 的合成以制备 [VO2(DMSO)4](CF3SO3)，并将其固定在聚对苯二甲酸乙二醇酯上用于催化应用

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2024-11-07 DOI:10.1134/S107032842460061X

P. A. Abramov, N. B. Kompan’kov, V. S. Sulyaeva, M. N. Sokolov

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引用次数: 0

摘要

本文探讨了从一种反应混合物中合成和分离 (Bu4N)3[H3V10O28] (I) 和 Na6[V10O28]-18H2O (II) 的各方面问题。对化合物 I 的合成过程进行了优化。化合物 I 和 HSO3CF3 在二甲基亚砜（DMSO）中反应生成络合物 [VO2(DMSO)4](CF3-SO3)（III）。图中显示了利用复合物 III 制备基于聚对苯二甲酸乙二醇酯 (PET) 的催化活性材料的可能性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Optimization of the Synthesis of Salts [V10O28]6– for the Preparation of [VO2(DMSO)4](CF3SO3) and Its Immobilization on Polyethylene Terephthalate for Catalytic Applications

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Optimization of the Synthesis of Salts [V10O28]6– for the Preparation of [VO2(DMSO)4](CF3SO3) and Its Immobilization on Polyethylene Terephthalate for Catalytic Applications

Aspects of the synthesis and isolation of (Bu₄N)₃[H₃V₁₀O₂₈] (I) and Na₆[V₁₀O₂₈]·18H₂O (II) from one reaction mixture are considered. The procedure for the synthesis of compound I is optimized. The reaction of compound I and HSO₃CF₃ in dimethyl sulfoxide (DMSO) affords complex [VO₂(DMSO)₄](CF₃-SO₃) (III). A possibility of using complex III for the preparation of catalytically active materials based on polyethylene terephthalate (PET) is shown.

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.