{"title":"MFM-300 中的动态金属配体键：利用半开放金属位点 \"教老狗学新招\"","authors":"Ricardo A. Peralta and Ilich A. Ibarra","doi":"10.1039/D4CE00865K","DOIUrl":null,"url":null,"abstract":"<p >Developing a deep understanding of the fascinating properties of MFM-300 (MFM = Manchester framework material) opens up a world of new and thrilling applications. The unique dynamic metal–ligand bonding for MFM-300(Sc) and MFM-300(In) is chronologically presented here, highlighting the exacting applications that were associated with such special behaviour (<em>i.e.</em>, description of complex NH<small><sub>3</sub></small> adsorption mechanisms, conversion of toxic H<small><sub>2</sub></small>S to polysulfides for promising fabrication of lithium–sulphur batteries and heterogeneous catalysis). This highlight aims to showcase the current advances in semi-open metal sites inherent to MFM-300(Sc) and MFM-300(In) to inspire new investigations to be carried out to develop new applications of this promising family of MOF materials.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 43","pages":" 6100-6107"},"PeriodicalIF":2.6000,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ce/d4ce00865k?page=search","citationCount":"0","resultStr":"{\"title\":\"Dynamic metal–ligand bonds in MFM-300: the use of semi-open metal sites to “teach an old dog new tricks”\",\"authors\":\"Ricardo A. Peralta and Ilich A. Ibarra\",\"doi\":\"10.1039/D4CE00865K\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Developing a deep understanding of the fascinating properties of MFM-300 (MFM = Manchester framework material) opens up a world of new and thrilling applications. The unique dynamic metal–ligand bonding for MFM-300(Sc) and MFM-300(In) is chronologically presented here, highlighting the exacting applications that were associated with such special behaviour (<em>i.e.</em>, description of complex NH<small><sub>3</sub></small> adsorption mechanisms, conversion of toxic H<small><sub>2</sub></small>S to polysulfides for promising fabrication of lithium–sulphur batteries and heterogeneous catalysis). This highlight aims to showcase the current advances in semi-open metal sites inherent to MFM-300(Sc) and MFM-300(In) to inspire new investigations to be carried out to develop new applications of this promising family of MOF materials.</p>\",\"PeriodicalId\":70,\"journal\":{\"name\":\"CrystEngComm\",\"volume\":\" 43\",\"pages\":\" 6100-6107\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-09-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2024/ce/d4ce00865k?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"CrystEngComm\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce00865k\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce00865k","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Dynamic metal–ligand bonds in MFM-300: the use of semi-open metal sites to “teach an old dog new tricks”
Developing a deep understanding of the fascinating properties of MFM-300 (MFM = Manchester framework material) opens up a world of new and thrilling applications. The unique dynamic metal–ligand bonding for MFM-300(Sc) and MFM-300(In) is chronologically presented here, highlighting the exacting applications that were associated with such special behaviour (i.e., description of complex NH3 adsorption mechanisms, conversion of toxic H2S to polysulfides for promising fabrication of lithium–sulphur batteries and heterogeneous catalysis). This highlight aims to showcase the current advances in semi-open metal sites inherent to MFM-300(Sc) and MFM-300(In) to inspire new investigations to be carried out to develop new applications of this promising family of MOF materials.
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