以水为氢供体光催化多组分合成含酯喹喔啉-2(1H)-酮

IF 9.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chinese Chemical Letters Pub Date : 2024-11-01 DOI:10.1016/j.cclet.2024.110582

Qiang Feng, Jindong Hao, Ya Hu, Rong Fu, Wei Wei, Dong Yi

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引用次数: 0

摘要

在水的存在下，开发了一种方便的烯烃、喹喔啉-2(1H)-酮和重氮化合物的多组分光催化反应。在室温条件下，可以有效地获得一些含酯的喹喔啉-2(1H)-酮，收率从中等到良好。这种无金属可见光驱动的串联反应是通过质子耦合电子转移（PCET）过程进行的，使用水作为氢供体，1,2,3,5-四（咔唑-9-基）-4,6-二氰基苯（4CzIPN）作为光催化剂。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Photocatalytic multi-component synthesis of ester-containing quinoxalin-2(1H)-ones using water as the hydrogen donor

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Photocatalytic multi-component synthesis of ester-containing quinoxalin-2(1H)-ones using water as the hydrogen donor

A convenient photocatalytic multi-component reaction of alkenes, quinoxalin-2(1H)-ones, and diazo compounds has been developed in the presence of water. A number of ester-containing quinoxalin-2(1H)-ones could be efficiently obtained in moderate to good yields at room temperature. This metal-free visible-light-driven tandem reaction was conducted through proton-coupled electron transfer (PCET) process using water as the hydrogen donor and 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) as the photocatalyst.

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来源期刊

Chinese Chemical Letters 化学-化学综合

CiteScore

14.10

自引率

15.40%

发文量

8969

审稿时长

1.6 months

期刊介绍： Chinese Chemical Letters (CCL) (ISSN 1001-8417) was founded in July 1990. The journal publishes preliminary accounts in the whole field of chemistry, including inorganic chemistry, organic chemistry, analytical chemistry, physical chemistry, polymer chemistry, applied chemistry, etc.Chinese Chemical Letters does not accept articles previously published or scheduled to be published. To verify originality, your article may be checked by the originality detection service CrossCheck.