封面:沸石框架中用于油酸甲酯环氧化的隔离四面体配位Ti(IV)位点的合理设计(Chem.)

IF 3.5 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Sorasak Klinyod, Krissanapat Yomthong, Ploychanok Iadrat, Pinit Kidkhunthod, Kittisak Choojun, Tawan Sooknoi, Chularat Wattanakit
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引用次数: 0

摘要

隔离的 Ti(IV)沸石已被合理地设计出来。由于各种沸石框架的铝拓扑密度不同,因此会产生不同程度的空位来容纳 Ti(IV) 活性位点。主沸石结构中的空位越多,孤立的四面体配位 Ti(IV)就越多,尤其是在 BEA 框架中,从而最终提高了油酸甲酯环氧化反应对 9,10-环氧硬脂酸甲酯的催化性能。更多详情,请参阅 Chularat Wattanakit 及其合作者发表的 e202400669 号文章。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Front Cover: Rational Design of Isolated Tetrahedrally Coordinated Ti(IV) Sites in Zeolite Frameworks for Methyl Oleate Epoxidation (Chem. Asian J. 20/2024)

Front Cover: Rational Design of Isolated Tetrahedrally Coordinated Ti(IV) Sites in Zeolite Frameworks for Methyl Oleate Epoxidation (Chem. Asian J. 20/2024)

Isolated Ti(IV)-zeolites have been rationally designed. The different aluminium topological densities of various zeolite frameworks lead to the creation of different degrees of vacant sites for hosting Ti(IV) active sites. The more vacancies in the host zeolite structure, the more isolated tetrahedrally coordinated Ti(IV) can be increased, especially in the BEA framework, eventually enhancing the catalytic performance in methyl oleate epoxidation towards methyl-9,10-epoxystearate. More details can be found in article number e202400669 by Chularat Wattanakit, and co-workers.

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来源期刊
Chemistry - An Asian Journal
Chemistry - An Asian Journal 化学-化学综合
CiteScore
7.00
自引率
2.40%
发文量
535
审稿时长
1.3 months
期刊介绍: Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).
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