作为合成阿洛贝杜酮 A-共衍生物的关键试剂的过硫酸-硫酸体系

IF 0.9 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2024-10-29 DOI:10.1134/S1070363224090081

M. P. Yakovleva, V. A. Vydrina, R. R. Sayakhov, G. Yu. Ishmuratov

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引用次数: 0

摘要

有人提出以二氯甲烷中的执行酸-硫酸体系为关键试剂，合成多种 allobetulone 的 A-seco 衍生物。结果，从相同的底物（allobetulone）和试剂（二氯甲烷中的甲酸）中，根据加入硫酸的量和方法的不同，得到了 4 种不同官能度的 allobetulon 衍生物（不饱和酸、酮酸、甲酰氧基酸和二元酸）。

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Performic Acid–Sulfuric Acid System as a Key Reagent for the Synthesis of Allobetulone A-seco-derivatives

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Performic Acid–Sulfuric Acid System as a Key Reagent for the Synthesis of Allobetulone A-seco-derivatives

The performic acid–sulfuric acid system in methylene chloride was proposed as a key reagent for the synthesis of a number of A-seco-derivatives of allobetulone. As a result, from the same substrate (allobetulone) and reagent (formic acid in methylene chloride), depending on different amounts and method of adding sulfuric acid, 4 differently functionalized derivatives of allobetulon (unsaturated acid, keto acid, formyloxy acid and diacid) were obtained.

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来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.