{"title":"过氧化氢催化剂晶粒尺寸对性能和老化的影响","authors":"","doi":"10.1016/j.actaastro.2024.10.046","DOIUrl":null,"url":null,"abstract":"<div><div>Two different diameters of Pt/Al<sub>2</sub>O<sub>3</sub> spherical catalysts (1 mm and 2 mm) for HTP 98 % decomposition were tested to compare the catalytic activity and catalyst ageing. Comparable decomposition performance efficiencies were obtained during thruster-like tests in a catalytic decomposition setup, even though the 1-mm showed a better reactivity and temperature rising time, including in cold-start operation. However, a rapid physical degradation accompanied by pressure peaks observed throughout testing of the 1-mm catalyst led to damage of the catalyst and apparition of fines, causing partial clogging of the bed.</div></div>","PeriodicalId":44971,"journal":{"name":"Acta Astronautica","volume":null,"pages":null},"PeriodicalIF":3.1000,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of hydrogen peroxide catalyst grain size on performance and ageing\",\"authors\":\"\",\"doi\":\"10.1016/j.actaastro.2024.10.046\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Two different diameters of Pt/Al<sub>2</sub>O<sub>3</sub> spherical catalysts (1 mm and 2 mm) for HTP 98 % decomposition were tested to compare the catalytic activity and catalyst ageing. Comparable decomposition performance efficiencies were obtained during thruster-like tests in a catalytic decomposition setup, even though the 1-mm showed a better reactivity and temperature rising time, including in cold-start operation. However, a rapid physical degradation accompanied by pressure peaks observed throughout testing of the 1-mm catalyst led to damage of the catalyst and apparition of fines, causing partial clogging of the bed.</div></div>\",\"PeriodicalId\":44971,\"journal\":{\"name\":\"Acta Astronautica\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2024-10-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta Astronautica\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0094576524006209\",\"RegionNum\":2,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, AEROSPACE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Astronautica","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0094576524006209","RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, AEROSPACE","Score":null,"Total":0}
Influence of hydrogen peroxide catalyst grain size on performance and ageing
Two different diameters of Pt/Al2O3 spherical catalysts (1 mm and 2 mm) for HTP 98 % decomposition were tested to compare the catalytic activity and catalyst ageing. Comparable decomposition performance efficiencies were obtained during thruster-like tests in a catalytic decomposition setup, even though the 1-mm showed a better reactivity and temperature rising time, including in cold-start operation. However, a rapid physical degradation accompanied by pressure peaks observed throughout testing of the 1-mm catalyst led to damage of the catalyst and apparition of fines, causing partial clogging of the bed.
期刊介绍:
Acta Astronautica is sponsored by the International Academy of Astronautics. Content is based on original contributions in all fields of basic, engineering, life and social space sciences and of space technology related to:
The peaceful scientific exploration of space,
Its exploitation for human welfare and progress,
Conception, design, development and operation of space-borne and Earth-based systems,
In addition to regular issues, the journal publishes selected proceedings of the annual International Astronautical Congress (IAC), transactions of the IAA and special issues on topics of current interest, such as microgravity, space station technology, geostationary orbits, and space economics. Other subject areas include satellite technology, space transportation and communications, space energy, power and propulsion, astrodynamics, extraterrestrial intelligence and Earth observations.