氯钌酰环戊三烯的合成与结构

IF 6.1 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Frontiers Pub Date : 2024-10-22 DOI:10.1039/d4qi01833h

Zhenwei Chu, Zhishun Peng, Xu Cheng, Yuhui Hua, Guomei He, Jiangxi CHEN, Guochen Jia

{"title":"氯钌酰环戊三烯的合成与结构","authors":"Zhenwei Chu, Zhishun Peng, Xu Cheng, Yuhui Hua, Guomei He, Jiangxi CHEN, Guochen Jia","doi":"10.1039/d4qi01833h","DOIUrl":null,"url":null,"abstract":"The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized by spectroscopic data and X-ray diffraction. In addition, computational studies provided the evidence for their aromatic character, making them as an important supplement to the rare aromatic ruthenacycle family.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":null,"pages":null},"PeriodicalIF":6.1000,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Structure of Chlororuthenacyclopentatriene\",\"authors\":\"Zhenwei Chu, Zhishun Peng, Xu Cheng, Yuhui Hua, Guomei He, Jiangxi CHEN, Guochen Jia\",\"doi\":\"10.1039/d4qi01833h\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized by spectroscopic data and X-ray diffraction. In addition, computational studies provided the evidence for their aromatic character, making them as an important supplement to the rare aromatic ruthenacycle family.\",\"PeriodicalId\":79,\"journal\":{\"name\":\"Inorganic Chemistry Frontiers\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.1000,\"publicationDate\":\"2024-10-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry Frontiers\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4qi01833h\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry Frontiers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4qi01833h","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

通过 RuCl2(PPh3)3 与邻苯基二炔衍生物在过量盐酸存在下的反应，首次实现了氯钌环五三烯。光谱数据和 X 射线衍射对这些独特的氯钌环的结构进行了全面表征。此外，计算研究还证明了它们的芳香特性，使它们成为稀有芳香钌环家族的重要补充。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Synthesis and Structure of Chlororuthenacyclopentatriene

The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized by spectroscopic data and X-ray diffraction. In addition, computational studies provided the evidence for their aromatic character, making them as an important supplement to the rare aromatic ruthenacycle family.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Inorganic Chemistry Frontiers CHEMISTRY, INORGANIC & NUCLEAR-

CiteScore

10.40

自引率

7.10%

发文量

587

审稿时长

1.2 months

期刊介绍： The international, high quality journal for interdisciplinary research between inorganic chemistry and related subjects