利用钕的共振电离光谱确定高效的两步电离方案

IF 3.2 2区化学 Q1 SPECTROSCOPY

Spectrochimica Acta Part B: Atomic Spectroscopy Pub Date : 2024-09-21 DOI:10.1016/j.sab.2024.107036

Masabumi Miyabe , Yoshihiro Iwata , Hideki Tomita , Masato Morita , Tetsuo Sakamoto

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引用次数: 0

摘要

对钕（Nd）进行了双色双步共振电离光谱分析，以确定 120 多个偶极自电离水平及其候选 J 值。通过对观测到的自电离里德堡系列进行分析，得出了 44,560.11 (43)stat (2)sys cm-1 的值，作为更准确的钕电离势。饱和法用于测量一些强电离转变的转变截面。根据测得的横截面，利用方案横截面公式评估了一些两步电离方案的电离效率，得出了几种可行的方案。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Resonance ionization spectroscopy of neodymium for determining a highly efficient two-step ionization scheme

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Resonance ionization spectroscopy of neodymium for determining a highly efficient two-step ionization scheme

Two-color two-step resonance ionization spectroscopy of neodymium (Nd) was performed to identify more than 120 even-parity autoionizing levels and their candidate J-values. The analysis of the observed autoionizing Rydberg series yielded a value of 44,560.11 (43)_stat (2)_sys cm⁻¹ as a more accurate ionization potential of Nd. The saturation method was used to measure the transition cross-sections for some intense ionization transitions. From the measured cross-sections, the ionization efficiencies of some two-step ionization schemes were evaluated using the scheme cross-section formula to obtain several promising schemes.

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来源期刊

Spectrochimica Acta Part B: Atomic Spectroscopy 物理-光谱学

CiteScore

6.10

自引率

12.10%

发文量

173

审稿时长

81 days

期刊介绍： Spectrochimica Acta Part B: Atomic Spectroscopy, is intended for the rapid publication of both original work and reviews in the following fields: Atomic Emission (AES), Atomic Absorption (AAS) and Atomic Fluorescence (AFS) spectroscopy; Mass Spectrometry (MS) for inorganic analysis covering Spark Source (SS-MS), Inductively Coupled Plasma (ICP-MS), Glow Discharge (GD-MS), and Secondary Ion Mass Spectrometry (SIMS). Laser induced atomic spectroscopy for inorganic analysis, including non-linear optical laser spectroscopy, covering Laser Enhanced Ionization (LEI), Laser Induced Fluorescence (LIF), Resonance Ionization Spectroscopy (RIS) and Resonance Ionization Mass Spectrometry (RIMS); Laser Induced Breakdown Spectroscopy (LIBS); Cavity Ringdown Spectroscopy (CRDS), Laser Ablation Inductively Coupled Plasma Atomic Emission Spectroscopy (LA-ICP-AES) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). X-ray spectrometry, X-ray Optics and Microanalysis, including X-ray fluorescence spectrometry (XRF) and related techniques, in particular Total-reflection X-ray Fluorescence Spectrometry (TXRF), and Synchrotron Radiation-excited Total reflection XRF (SR-TXRF). Manuscripts dealing with (i) fundamentals, (ii) methodology development, (iii)instrumentation, and (iv) applications, can be submitted for publication.