S. M. Orlyk, N. V. Vlasenko, V. I. Chedryk, A. Y. Kapran, S. Dzwigaj
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引用次数: 0
摘要
根据准平衡 NH3 和 CO2 热脱附数据，确定了不同 Si/Al 比的含锌 BEA 沸石组成中的铬对其在有或无 CO2 的丙烷脱氢制丙烯过程中的酸碱特性和催化性能的影响。发现基于初始 Cr/ZnAlBEA 沸石（Si/Al = 17）的催化剂对丙烷转化率和丙烯选择性有积极影响。与不含二氧化碳的丙烷脱氢工艺相比，在有二氧化碳参与的丙烷脱氢工艺中，丙烷转化率更高，但丙烯选择性较低。
Influence of Chromium in Cr/Zn-Bea Metal–Zeolite Composites on Their Acid–Base Characteristics and Catalytic Properties in the Processes of Propane Dehydrogenation
According to the quasi-equilibrium NH3 and CO2 thermal desorption data, the effect of chromium in the composition of zinc-containing BEA zeolites with different Si/Al ratios on their acid–base characteristics and catalytic properties in the process of dehydrogenation of propane to propene with or without CO2 has been determined. A positive effect on the propane conversion and the propene selectivity is found for a catalyst based on the initial Cr/ZnAlBEA zeolite (Si/Al = 17). Higher propane conversion is achieved in the process of propane dehydrogenation with the participation of CO2 in the presence of Cr/Zn-BEA catalysts, but with lower propene selectivity when compared to the propane dehydrogenation process without CO2.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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