烯烃的苯基硒三氟甲氧基化。

IF 2.2 4区化学 Q2 CHEMISTRY, ORGANIC

Beilstein Journal of Organic Chemistry Pub Date : 2024-09-26 eCollection Date: 2024-01-01 DOI:10.3762/bjoc.20.207

Clément Delobel, Armen Panossian, Gilles Hanquet, Frédéric R Leroux, Fabien Toulgoat, Thierry Billard

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引用次数: 0

摘要

三氟甲氧基化分子和硒化化合物有着广泛而有趣的应用，但它们是分开的。为了将这两种模式的潜力结合起来，并提出一类新的化合物，我们开发了一种烯烃的亲电苯基硒化三氟甲氧基化反应，这种反应会产生β-硒化的三氟甲氧基化化合物，或者在随后的还原反应中产生三氟甲氧基化化合物。

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Phenylseleno trifluoromethoxylation of alkenes.

Trifluoromethoxylated molecules and selenylated compounds find a wide range of interesting applications, but separately. In order to combine the potential of these two motifs and to propose a new class of compounds, we have developed an electrophilic phenylseleno trifluoromethoxylation of alkenes, which leads to β-selenylated trifluoromethoxylated compounds or, upon subsequent reduction, to the trifluoromethoxylated ones.

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来源期刊

Beilstein Journal of Organic Chemistry 化学-有机化学

CiteScore

4.90

自引率

3.70%

发文量

167

审稿时长

1.4 months

期刊介绍： The Beilstein Journal of Organic Chemistry is an international, peer-reviewed, Open Access journal. It provides a unique platform for rapid publication without any charges (free for author and reader) – Platinum Open Access. The content is freely accessible 365 days a year to any user worldwide. Articles are available online immediately upon publication and are publicly archived in all major repositories. In addition, it provides a platform for publishing thematic issues (theme-based collections of articles) on topical issues in organic chemistry. The journal publishes high quality research and reviews in all areas of organic chemistry, including organic synthesis, organic reactions, natural product chemistry, structural investigations, supramolecular chemistry and chemical biology.