2,3-双(2-吡啶基)噻吩并[3,4-b]吡嗪及其钌(II)配合物：一种用于增强金属间通讯的新型双齿桥接配体

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2024-09-27 DOI:10.1039/d4dt02495h

Kristine L. Konkol, Wyatt D. Wilcox, Seth C. Rasmussen

引用次数: 0

摘要

报告了一种新的双齿桥接配体--双(2-吡啶基)噻吩并[3,4-b]吡嗪，并以其单金属和双金属 Ru(II) 复合物为代表。报告对这些物质进行了光谱、电化学和 X 射线晶体学表征，双金属配合物的两个 Ru(III)/Ru(II) 偶联物的分离表明，金属与金属之间的交流比传统的多吡啶类似物更好。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

2,3-Bis(2-pyridyl)thieno[3,4-b]pyrazine and its ruthenium(II) complexes: a new bidentate bridging ligand for enhanced metal–metal communication

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2,3-Bis(2-pyridyl)thieno[3,4-b]pyrazine and its ruthenium(II) complexes: a new bidentate bridging ligand for enhanced metal–metal communication

A new bidentate bridging ligand, bis(2-pyridyl)thieno[3,4-b]pyrazine is reported, along with its mono- and bi-metallic Ru(II) complexes as representative examples. Spectroscopic, electrochemical and X-ray crystallographic characterization of these species is reported, with the separation of the two Ru(III)/Ru(II) couples of the bimetallic complex suggesting better metal–metal communication than classical polypyridyl analogues.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.