用于合成八元环的可见光诱导过环级联反应

IF 1.5 4区化学 Q3 CHEMISTRY, ORGANIC

Tetrahedron Letters Pub Date : 2024-09-19 DOI:10.1016/j.tetlet.2024.155309

引用次数: 0

摘要

本文介绍了一种可见光诱导的合成八元环的周环级联反应。该反应通过[2 + 2]-光环加成、碱促进消除和逆-4π-电环化进行。该反应具有广泛的底物范围和良好的官能团耐受性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Visible light-induced pericyclic cascade reaction for the synthesis of eight-membered rings

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Visible light-induced pericyclic cascade reaction for the synthesis of eight-membered rings

A visible light-induced pericyclic cascade reaction for the synthesis of eight-membered rings is described. The reaction proceeds via [2 + 2]-photocycloaddition, base-promoted elimination, and retro-4π-electrocyclization. It exhibits broad substrate scope and good functional group tolerance.

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来源期刊

Tetrahedron Letters 化学-有机化学

CiteScore

3.50

自引率

5.60%

发文量

521

审稿时长

28 days

期刊介绍： Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.