A dual-chambered microbial fuel cell with manganese dioxide nano-structured cathode for wastewater treatment.

Microbial fuel cells (MFCs) can generate electricity by breaking down organic molecules through sustainable bio-electrochemical processes and wastewater as an energy source. A novel approach to remediate wastewater containing selenite was studied utilizing a selenite-reducing mixed bacterial culture with a nano manganese oxide modified cathode in the MFCs. The modification enhanced electrochemical catalytic activity, extracellular electron transfer rate, chemical oxygen demand (COD) elimination efficiency, and coulombic efficiency. Scanning electron microscopy and energy dispersive x-rays analysis were used to examine a manganese dioxide-coated graphite cathode's surface morphology and chemical composition. The manganese dioxide-coated electrode generated up to 69% higher voltage with 150 ppm selenite concentration than the uncoated graphite electrode. The MFC removed up to 80% of the initial COD of 120 mg l^-1and achieved a maximum power density of 1.51 W m^-2. The study demonstrates that MFCs can effectively treat selenite-containing wastewater, and modifying the cathode can enhance energy production.