用于氧化还原液流电池的铁/铁氰化物的现状

IF 7.9 2区化学 Q1 CHEMISTRY, PHYSICAL

Current Opinion in Electrochemistry Pub Date : 2024-08-28 DOI:10.1016/j.coelec.2024.101581

Maryam Mouselly , Hussain Alawadhi , Sirugaloor Thangavel Senthilkumar

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引用次数: 0

摘要

铁/铁氰化物偶联物因其有利的电化学特性、用户友好性和经济实惠的成本，已被广泛研究用作各种氧化还原液流电池（RFB）中的氧化还原物种。然而，高浓度和稳定的铁氰化物对开发高能量密度和长循环寿命的 RFB 十分重要。人们探索了不同的方法，通过不同的离子效应和阳离子修饰来提高其浓度，同时还探索了 pH 值、光和空气敏感性对其稳定性的影响。本综述将概述有关提高铁/铁氰化物浓度及其在射频电池中稳定性的最新研究。

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Current status of ferro-/ferricyanide for redox flow batteries

The ferro-/ferricyanide couple has been extensively investigated as a redox species in various redox flow batteries (RFBs) due to its advantageous electrochemical properties, user-friendliness, and affordable cost. However, the high concentration and stability of ferro-/ferricyanide are important for developing high-energy density and long-cycle life RFBs. Different methods have been explored to increase its concentration through diverse ion effects and cation modification while also exploring the effects of pH, light, and air sensitivity on its stability. This review will provide an overview of recent research on the concentration enhancement of ferro-/ferricyanide and its stability for RFBs.

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来源期刊

Current Opinion in Electrochemistry Chemistry-Analytical Chemistry

CiteScore

14.00

自引率

5.90%

发文量

272

审稿时长

73 days

期刊介绍： The development of the Current Opinion journals stemmed from the acknowledgment of the growing challenge for specialists to stay abreast of the expanding volume of information within their field. In Current Opinion in Electrochemistry, they help the reader by providing in a systematic manner: 1.The views of experts on current advances in electrochemistry in a clear and readable form. 2.Evaluations of the most interesting papers, annotated by experts, from the great wealth of original publications. In the realm of electrochemistry, the subject is divided into 12 themed sections, with each section undergoing an annual review cycle: • Bioelectrochemistry • Electrocatalysis • Electrochemical Materials and Engineering • Energy Storage: Batteries and Supercapacitors • Energy Transformation • Environmental Electrochemistry • Fundamental & Theoretical Electrochemistry • Innovative Methods in Electrochemistry • Organic & Molecular Electrochemistry • Physical & Nano-Electrochemistry • Sensors & Bio-sensors •