{"title":"吡啶-2-基氨基甲酸乙酯与苯乙酰溴的季铵化反应","authors":"D. A. Lomov","doi":"10.1134/S1070428024060204","DOIUrl":null,"url":null,"abstract":"<p>The reaction of ethyl pyridine-2-ylcarbamate with phenacyl bromides in acetonitrile gave 2-aryl-1-(ethoxycarbonyl)-2-hydroxy-2-phenyl-2,3-dihydro-1<i>H</i>-imidazo[1,2-<i>a</i>]pyridine-4-ium bromides which were converted into 2-arylimidazo[1,2-<i>a</i>]pyridines by heating in acetic anhydride, followed by treatment with potassium carbonate.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"60 6","pages":"1145 - 1148"},"PeriodicalIF":0.8000,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Quaternization of Ethyl Pyridin-2-ylcarbamate with Phenacyl Bromides\",\"authors\":\"D. A. Lomov\",\"doi\":\"10.1134/S1070428024060204\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The reaction of ethyl pyridine-2-ylcarbamate with phenacyl bromides in acetonitrile gave 2-aryl-1-(ethoxycarbonyl)-2-hydroxy-2-phenyl-2,3-dihydro-1<i>H</i>-imidazo[1,2-<i>a</i>]pyridine-4-ium bromides which were converted into 2-arylimidazo[1,2-<i>a</i>]pyridines by heating in acetic anhydride, followed by treatment with potassium carbonate.</p>\",\"PeriodicalId\":766,\"journal\":{\"name\":\"Russian Journal of Organic Chemistry\",\"volume\":\"60 6\",\"pages\":\"1145 - 1148\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-08-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Organic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070428024060204\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070428024060204","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Quaternization of Ethyl Pyridin-2-ylcarbamate with Phenacyl Bromides
The reaction of ethyl pyridine-2-ylcarbamate with phenacyl bromides in acetonitrile gave 2-aryl-1-(ethoxycarbonyl)-2-hydroxy-2-phenyl-2,3-dihydro-1H-imidazo[1,2-a]pyridine-4-ium bromides which were converted into 2-arylimidazo[1,2-a]pyridines by heating in acetic anhydride, followed by treatment with potassium carbonate.
期刊介绍:
Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.