{"title":"非绝热相互作用对 CN 自由基的 X 2Σ+ ~ A 2Π ~ B 2Σ+ 复合物的兰德 g 系数的影响","authors":"S. V. Kozlov, A. V. Stolyarov, E. A. Pazyuk","doi":"10.1134/S0030400X24030111","DOIUrl":null,"url":null,"abstract":"<p>The effect of the electron-rotational interaction induced by an external magnetic field on the values of Lande <i>g</i>-factors is systematically investigated within the quantum mechanical model of coupled radial Schredinger equations for locally and regularly perturbed electronic-vibrational-rotational (rovibronic) levels of nonadiabatically coupled <i>X</i> <sup>2</sup>Σ<sup>+</sup>, <i>A</i><sup>2</sup>Π and <i>B</i><sup>2</sup>Σ<sup>+</sup> states of the CN radical, whose isotopomers are of persistent astronomical interest due to their wide use in optical diagnostics of various regions of the interstellar and near-stellar medium.</p>","PeriodicalId":723,"journal":{"name":"Optics and Spectroscopy","volume":"132 3","pages":"262 - 269"},"PeriodicalIF":0.8000,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of Non-Adiabatic Interactions on the Lande g-Factors of the X 2Σ+ ~ A 2Π ~ B 2Σ+ Complex of the CN Radical\",\"authors\":\"S. V. Kozlov, A. V. Stolyarov, E. A. Pazyuk\",\"doi\":\"10.1134/S0030400X24030111\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The effect of the electron-rotational interaction induced by an external magnetic field on the values of Lande <i>g</i>-factors is systematically investigated within the quantum mechanical model of coupled radial Schredinger equations for locally and regularly perturbed electronic-vibrational-rotational (rovibronic) levels of nonadiabatically coupled <i>X</i> <sup>2</sup>Σ<sup>+</sup>, <i>A</i><sup>2</sup>Π and <i>B</i><sup>2</sup>Σ<sup>+</sup> states of the CN radical, whose isotopomers are of persistent astronomical interest due to their wide use in optical diagnostics of various regions of the interstellar and near-stellar medium.</p>\",\"PeriodicalId\":723,\"journal\":{\"name\":\"Optics and Spectroscopy\",\"volume\":\"132 3\",\"pages\":\"262 - 269\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-09-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Optics and Spectroscopy\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0030400X24030111\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"OPTICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optics and Spectroscopy","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1134/S0030400X24030111","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"OPTICS","Score":null,"Total":0}
引用次数: 0
摘要
摘要 在耦合径向施雷丁格方程的量子力学模型中,系统地研究了外磁场诱导的电子旋转相互作用对非辐射耦合 X 2Σ+ 的兰德 g 因子值的影响、由于这些同素异形体广泛用于星际和近星介质各区域的光学诊断,因此在天文学上一直很受关注。
Influence of Non-Adiabatic Interactions on the Lande g-Factors of the X 2Σ+ ~ A 2Π ~ B 2Σ+ Complex of the CN Radical
The effect of the electron-rotational interaction induced by an external magnetic field on the values of Lande g-factors is systematically investigated within the quantum mechanical model of coupled radial Schredinger equations for locally and regularly perturbed electronic-vibrational-rotational (rovibronic) levels of nonadiabatically coupled X2Σ+, A2Π and B2Σ+ states of the CN radical, whose isotopomers are of persistent astronomical interest due to their wide use in optical diagnostics of various regions of the interstellar and near-stellar medium.
期刊介绍:
Optics and Spectroscopy (Optika i spektroskopiya), founded in 1956, presents original and review papers in various fields of modern optics and spectroscopy in the entire wavelength range from radio waves to X-rays. Topics covered include problems of theoretical and experimental spectroscopy of atoms, molecules, and condensed state, lasers and the interaction of laser radiation with matter, physical and geometrical optics, holography, and physical principles of optical instrument making.