在氯化钠溶液中制备α-半水石膏过程中的钠掺入与控制

IF 5.9 3区 工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY
Xianbo Li, Lusong Wang
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引用次数: 0

摘要

磷石膏(PG)在钠盐溶液中转化为α-半水石膏(α-HH)的过程会受到 Na 掺杂的干扰,从而导致 Na 掺杂的α-HH 出现结霜现象。本研究阐明了在 95 ℃ 水热过程中 Na 杂质在 α-HH 中的含量演变,观察并控制了含有 Na 杂质的硬化石膏的结霜现象。结果表明,将初始 NaCl 浓度从 5 % 提高到 25 % 可在 30 分钟内促进 PG 向 α-HH 的相转化,但这会使产品中的 NaO 含量从 0.08 % 增加到 4.37 %,这是由于形成了不良相 NaSO-5CaSO-3HO。进入 α-HH 的 Na 杂质含量随 NaCl 溶液浓度和反应时间呈非线性增加,这可以用波尔兹曼函数很好地描述。掺入 Na 的 α-HH 硬化石膏在固化 3 d 后可观察到明显的结霜现象,经鉴定结霜为 NaSO。这项工作进一步证明了在 NaCl 溶液中添加 CaCl 是控制 Na 掺杂到 α-HH 中的有效方法的可行性,在 17.5 % NaCl 和 10 % CaCl 的混合溶液中,NaO 含量降至 0.97 %,这有助于消除霜冻现象并提高 α-HH 的机械强度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Sodium doping and control during the preparation of α-hemihydrate gypsum in NaCl solution
Transformation of phosphogypsum (PG) into α-hemihydrate gypsum (α-HH) in sodium salt solution is disturbed by the doping of Na, which causes the frost of Na doped α-HH. In this study, the content evolution of Na impurities into α-HH was clarified during the hydrothermal process at 95 ℃, the frost phenomenon of hardened gypsum containing Na impurities was observed and controlled. The results show that increasing the initial NaCl concentration from 5 % to 25 % can promote the phase conversion of PG into α-HH within 30 min, but this will increase the NaO content in the product from 0.08 % to 4.37 %, which is due to the formation of the undesirable phase NaSO·5CaSO·3HO. The content of Na impurities entering α-HH presents a non-linear increase with the NaCl solution concentration and reaction time, which can be well described by Boltzmann function. An obvious frost phenomenon of the hardened plaster of Na doped α-HH can be observed after curing 3 d, and the frost is identified as NaSO. This work further demonstrates the feasibility that the addition of CaCl in NaCl solution is an effective approach to control the doping of Na into α-HH, the NaO content decreases to 0.97 % in the mixed solution of 17.5 % NaCl and 10 % CaCl, this helps to eliminate the frost phenomenon and improve the mechanical strength of α-HH.
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来源期刊
CiteScore
10.40
自引率
6.60%
发文量
639
审稿时长
29 days
期刊介绍: Journal of Industrial and Engineering Chemistry is published monthly in English by the Korean Society of Industrial and Engineering Chemistry. JIEC brings together multidisciplinary interests in one journal and is to disseminate information on all aspects of research and development in industrial and engineering chemistry. Contributions in the form of research articles, short communications, notes and reviews are considered for publication. The editors welcome original contributions that have not been and are not to be published elsewhere. Instruction to authors and a manuscript submissions form are printed at the end of each issue. Bulk reprints of individual articles can be ordered. This publication is partially supported by Korea Research Foundation and the Korean Federation of Science and Technology Societies.
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