{"title":"第 II 章.气体在大气压和高压下点燃和爆炸的连锁性质","authors":"V. V. Azatyan","doi":"10.1134/S0023158424601268","DOIUrl":null,"url":null,"abstract":"<p>The reasons for the mistakes underlying the neglect and denial of the reaction chains discovered by N.N. Semenov and S. Hinshelwood in the combustion of gases at pressures close to atmospheric are analyzed. A method for unequivocal experimental proof of the chain nature of gas combustion is described. Examples are given proving the chain nature of combustion and explosion in a wide range of pressures and temperatures.</p>","PeriodicalId":682,"journal":{"name":"Kinetics and Catalysis","volume":"65 1 supplement","pages":"S11 - S24"},"PeriodicalIF":1.3000,"publicationDate":"2024-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Chapter II. Chain Nature of Ignition and Explosion of Gases at Atmospheric and High Pressures\",\"authors\":\"V. V. Azatyan\",\"doi\":\"10.1134/S0023158424601268\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The reasons for the mistakes underlying the neglect and denial of the reaction chains discovered by N.N. Semenov and S. Hinshelwood in the combustion of gases at pressures close to atmospheric are analyzed. A method for unequivocal experimental proof of the chain nature of gas combustion is described. Examples are given proving the chain nature of combustion and explosion in a wide range of pressures and temperatures.</p>\",\"PeriodicalId\":682,\"journal\":{\"name\":\"Kinetics and Catalysis\",\"volume\":\"65 1 supplement\",\"pages\":\"S11 - S24\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2024-08-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Kinetics and Catalysis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0023158424601268\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Kinetics and Catalysis","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0023158424601268","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
摘要 分析了忽视和否认 N.N. Semenov 和 S. Hinshelwood 在接近大气压的气体燃烧中发现的反应链的错误原因。介绍了通过实验明确证明气体燃烧链式性质的方法。举例说明了在各种压力和温度下燃烧和爆炸的链式性质。
Chapter II. Chain Nature of Ignition and Explosion of Gases at Atmospheric and High Pressures
The reasons for the mistakes underlying the neglect and denial of the reaction chains discovered by N.N. Semenov and S. Hinshelwood in the combustion of gases at pressures close to atmospheric are analyzed. A method for unequivocal experimental proof of the chain nature of gas combustion is described. Examples are given proving the chain nature of combustion and explosion in a wide range of pressures and temperatures.
期刊介绍:
Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.