合成沸石存在下二元-阿尔德反应中丙烯腈与环戊二烯的相互作用动力学

IF 1.3 4区化学 Q4 CHEMISTRY, PHYSICAL

Kinetics and Catalysis Pub Date : 2024-09-04 DOI:10.1134/S0023158424601633

D. Sh. Fakhretdinov, I. Sh. Yakupov, A. I. Iskhakova, E. R. Latypova, R. F. Talipov

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引用次数: 0

摘要

摘要研究了丙烯腈（AN）和环戊二烯（CPD）在工业沸石存在下通过 Diels-Alder 反应相互作用的形式动力学。研究揭示了相互作用组分的反应速率常数与多孔材料几何特性的关系。研究表明，在有沸石存在的情况下，反应的速率常数低于无多孔材料时的速率常数。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Kinetics of the Interaction of Acrylonitrile with Cyclopentadiene in the Diels–Alder Reaction in the Presence of Synthetic Zeolites

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Kinetics of the Interaction of Acrylonitrile with Cyclopentadiene in the Diels–Alder Reaction in the Presence of Synthetic Zeolites

The formal kinetics of the interaction of acrylonitrile (AN) and cyclopentadiene (CPD) by the Diels–Alder reaction in the presence of industrial zeolites has been studied. The dependence of the reaction rate constants of interacting components on the geometric properties of porous materials was revealed. The established dependence had a negative extremum at a zeolite pore diameter of 4 Å. It was shown that, in the presence of zeolites, the rate constant of the reaction under consideration was lower than that in the reaction carried out without porous materials.

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来源期刊

Kinetics and Catalysis 化学-物理化学

CiteScore

2.10

自引率

27.30%

发文量

审稿时长

6-12 weeks

期刊介绍： Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.