第 VI 章.作为异常临界现象实例的肼点燃和爆炸的特殊性

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-08-20 DOI:10.1134/S002315842460130X

V. V. Azatyan

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引用次数: 0

摘要

摘要根据前几章研究中提出的非等温链式反应理论，对一种重要技术产品--肼的热解和燃烧的反常行为给出了经实验验证的解释。此外，还解释了 N2H3 自由基的动力学特征，这些特征导致了肼氧点火半岛的不寻常特性。易点燃和爆炸的机理也得到了澄清。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Chapter VI. Specificities of Hydrazine Ignition and Explosion as an Example of Anomalous Critical Phenomena

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Chapter VI. Specificities of Hydrazine Ignition and Explosion as an Example of Anomalous Critical Phenomena

Based on the theory of nonisothermal chain reactions developed in the studies presented in the previous chapters, an experimentally verified explanation is given for the anomalous behavior of pyrolysis and combustion of a technically important product—hydrazine. The revealed kinetic features of N₂H₃ radicals, which led to the unusual properties of the hydrazine-oxygen ignition peninsula, are also explained. The mechanism of easy ignition and explosion has been clarified.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.