{"title":"第 V 章 气体燃烧中活性粒子之间的均相和异相反应","authors":"V. V. Azatyan","doi":"10.1134/S0023158424601293","DOIUrl":null,"url":null,"abstract":"<p>The formation of atoms and radicals in the flame in concentrations by many orders of magnitude higher than the equilibrium values at combustion temperatures is explained. Results that prove the important role of homogeneous and heterogeneous reactions between atoms and radicals in combustion are presented. The decisive role of previously unknown reactions of heterogeneous chain propagation in combustion is illustrated by experimental results. The reasons for the misconceptions of several foreign and Russian authors who tried to deny chain combustion are explained.</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Chapter V. Homogeneous and Heterogeneous Reactions between Active Particles in Gas Combustion\",\"authors\":\"V. V. Azatyan\",\"doi\":\"10.1134/S0023158424601293\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The formation of atoms and radicals in the flame in concentrations by many orders of magnitude higher than the equilibrium values at combustion temperatures is explained. Results that prove the important role of homogeneous and heterogeneous reactions between atoms and radicals in combustion are presented. The decisive role of previously unknown reactions of heterogeneous chain propagation in combustion is illustrated by experimental results. The reasons for the misconceptions of several foreign and Russian authors who tried to deny chain combustion are explained.</p>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-08-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0023158424601293\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0023158424601293","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Chapter V. Homogeneous and Heterogeneous Reactions between Active Particles in Gas Combustion
The formation of atoms and radicals in the flame in concentrations by many orders of magnitude higher than the equilibrium values at combustion temperatures is explained. Results that prove the important role of homogeneous and heterogeneous reactions between atoms and radicals in combustion are presented. The decisive role of previously unknown reactions of heterogeneous chain propagation in combustion is illustrated by experimental results. The reasons for the misconceptions of several foreign and Russian authors who tried to deny chain combustion are explained.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.