对叠层微孔层进行梯度疏水和厚度调节处理,以提高质子交换膜燃料电池的性能

IF 2.4 4区 化学 Q3 CHEMISTRY, PHYSICAL
Ionics Pub Date : 2024-09-06 DOI:10.1007/s11581-024-05817-6
Haihang Zhang, Haiming Chen, Juyuan Dong, Chongxue Zhao, Weimin Yang, Guangyi Lin
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引用次数: 0

摘要

本文基于梯度孔径原理,使用三种不同粒径的导电炭黑制备了具有三个微孔层的阴极气体扩散层。研究了微孔层的厚度,并设计了梯度疏水结构。目的是通过调整微孔层的制备参数,最大限度地提高电池的输出性能。各样品的物理和电化学特性表明,微孔层厚度的改变重新分配了气体扩散层的孔径分布,特别是增加了 20-40 µm 范围内的孔径数量。它们提高了气体扩散层在高电流密度下的液态水传输能力。微孔层的梯度疏水结构促进了阴极气体扩散层及时排出液态水,保证了氧气供应。结果表明,当微孔层厚度为 60 µm.三种微孔层中的疏水剂含量分别为 10 wt%、20 wt% 和 30 wt%,在 40%、60% 和 100% 三种湿度条件下,极限功率密度分别为 0.883、0.916 和 0.863 W/cm2。与最佳厚度相同但没有梯度疏水结构的样品相比,极限功率密度分别提高了 17.1%、12.0% 和 18.1%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Gradient hydrophobicity and thickness regulation treatment of stacked microporous layers to improve proton exchange membrane fuel cell performance

Gradient hydrophobicity and thickness regulation treatment of stacked microporous layers to improve proton exchange membrane fuel cell performance

In this paper, based on the principle of gradient aperture, a cathode gas diffusion layer with three microporous layers was prepared using conductive carbon black with three different particle sizes. The thickness of the microporous layers was studied, and a gradient hydrophobic structure was designed. The purpose was to maximize the output performance of the cell by adjusting the preparation parameters of the microporous layers. The physical and electrochemical properties of each sample showed that the change in micropore layer thickness redistributed the pore size distribution of the gas diffusion layer, especially increasing the number of pore sizes in the range of 20–40 µm. They improved the liquid water transport capacity of the gas diffusion layer at high current density. The gradient hydrophobic structure of the microporous layer promoted the cathode gas diffusion layer to expel liquid water in time and ensure the oxygen supply. The results showed that when the microporous layer thickness was 60 µm. The hydrophobic agent content in the three microporous layers was 10 wt%, 20 wt%, and 30 wt%, respectively, the limiting power densities of 0.883, 0.916, and 0.863 W/cm2 could be achieved under the three humidity conditions of 40%, 60%, and 100%, respectively. The limiting power density increased by 17.1%, 12.0%, and 18.1%, respectively, compared with the samples with the same optimal thickness but no gradient hydrophobic structure.

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来源期刊
Ionics
Ionics 化学-电化学
CiteScore
5.30
自引率
7.10%
发文量
427
审稿时长
2.2 months
期刊介绍: Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.
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