Jingjing Cui, Yiyi He, Cauê P. Souza, Jonas Weiser, Maximilian Dietz, Ivo Krummenacher, Rian D. Dewhurst, Holger Braunschweig, Felipe Fantuzzi
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Single‐Electron Oxidation, Chloride Abstraction, and Hydride‐Induced Decomposition of a Dichloro‐Bis(Germylene)
In this work we explore the reactivity of a dichloro‐bis(germylene) compound that features a naphthyridine diimine (NDI) ligand, denoted NDI‐Ge 2Cl2. Upon reaction with the oxidant [Cp2Fe][BArF4] (Cp = C5H5, BArF4 = [{3,5‐(CF3)2C6H3}4B]), we observed the formation of the radical species [NDI‐Ge2Cl2]•+[BArF4]−. Furthermore, the introduction of Na[BArF4] induced a single chloride anion abstraction process, resulting in the formation of [NDI‐Ge2Cl][BArF4]. The addition of Li[HB(sBu)3] to NDI‐Ge2Cl2 led to the generation of NDI‐Ge, presumably via a Cl/H exchange pathway followed by a decomposition process.
期刊介绍:
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
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