二氯双（亚甲基）的单电子氧化、氯化物萃取和氢化物诱导分解

IF 2.2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2024-08-23 DOI:10.1002/ejic.202400422

Jingjing Cui, Yiyi He, Cauê P. Souza, Jonas Weiser, Maximilian Dietz, Ivo Krummenacher, Rian D. Dewhurst, Holger Braunschweig, Felipe Fantuzzi

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引用次数: 0

摘要

在这项研究中，我们探索了一种二氯双（亚甲基）化合物的反应性，该化合物具有萘啶二亚胺（NDI）配体，命名为 NDI-Ge 2Cl2。与氧化剂 [Cp2Fe][BArF4]（Cp = C5H5，BArF4 = [{3,5-(CF3)2C6H3}4B]）反应后，我们观察到形成了自由基物种 [NDI-Ge2Cl2]-+[BArF4]-。此外，Na[BArF4]的引入诱导了单个氯阴离子的抽取过程，从而形成了[NDI-Ge2Cl][BArF4]。在 NDI-Ge2Cl2 中加入 Li[HB(sBu)3] 会生成 NDI-Ge，这可能是通过 Cl/H 交换途径，然后再进行分解过程。

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Single‐Electron Oxidation, Chloride Abstraction, and Hydride‐Induced Decomposition of a Dichloro‐Bis(Germylene)

In this work we explore the reactivity of a dichloro‐bis(germylene) compound that features a naphthyridine diimine (NDI) ligand, denoted NDI‐Ge 2Cl2. Upon reaction with the oxidant [Cp2Fe][BArF4] (Cp = C5H5, BArF4 = [{3,5‐(CF3)2C6H3}4B]), we observed the formation of the radical species [NDI‐Ge2Cl2]•+[BArF4]−. Furthermore, the introduction of Na[BArF4] induced a single chloride anion abstraction process, resulting in the formation of [NDI‐Ge2Cl][BArF4]. The addition of Li[HB(sBu)3] to NDI‐Ge2Cl2 led to the generation of NDI‐Ge, presumably via a Cl/H exchange pathway followed by a decomposition process.

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.