[C_{2}mim][CH_{3}SO_{3}]$--一种合适的新型导热流体?第 2 部分:其与水混合物的热物理性质

Francisco E. B. Bioucas, Carla S. G. P. Queirós, Daniel Lozano-Martín, M. S. Ferreira, Xavier Paredes, Ângela F. Santos, Fernando J. V. Santos, Manuel L. M. Lopes, Isabel M. S. Lampreia, Maria José V. Lourenço, Carlos A. Nieto de Castro, Klemens Massonne
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引用次数: 0

摘要

事实证明,离子液体是优秀的传热液体,是工业中热交换器和其他传热设备所用普通 HTF 的替代品。然而,离子液体的工业应用取决于其每公斤的生产成本,与联苯和氧化二苯基、烷基芳烃和二甲基聚硅氧烷油相比,离子液体在工业应用中具有竞争力。导热流体的效率取决于影响对流传热的基本热物理性质(密度、热容量、热导率和粘度),因为这些性质是计算不同热交换器几何形状的传热系数所必需的。在第 1 部分中,研究了纯 1-乙基-3-甲基咪唑鎓甲烷磺酸盐 $[C_{2}mim][CH_{3}SO_{3}]$(化学文摘社编号:145022-45-3)(ECOENG 110)的热物理性质,该产品由巴斯夫公司生产,商品名为 Basionics ST35,化验值为 $\geq$97% 含 $\leq$0.本文报告了[C2mim][CH3SO3]与水的混合物在整个浓度范围内,在 $P$ = 0.1 MPa 时的热物理性质。测量的特性包括密度和声速(293.15 < $T$/K < 343.15)、粘度、电导率和热导率、折射率(293.15 < $T$/K < 353.15)以及离子液体在水中的无限稀释扩散系数(298.15 K)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
$[C_{2}mim][CH_{3}SO_{3}]$ -- A Suitable New Heat Transfer Fluid? Part 2: Thermophysical Properties of Its Mixtures with Water
Ionic liquids have proved to be excellent heat transfer fluids and alternatives to common HTFs used in industries for heat exchangers and other heat transfer equipment. However, its industrial utilization depends on the cost per kg of its production, to be competitive for industrial applications with biphenyl and diphenyl oxide, alkylated aromatics, and dimethyl polysiloxane oils, which degrade above 200 {\deg}C and possess some environmental problems. The efficiency of a heat transfer fluid depends on the fundamental thermophysical properties influencing convective heat transfer (density, heat capacity, thermal conductivity, and viscosity), as these properties are necessary to calculate the heat transfer coefficients for different heat exchanger geometries. In Part 1, the thermophysical properties of pure 1-ethyl-3-methylimidazolium methanesulfonate $[C_{2}mim][CH_{3}SO_{3}]$ (CAS no. 145022-45-3), (ECOENG 110), produced by BASF, under the trade name of Basionics ST35, with an assay $\geq$97% with $\leq$0.5% water and $\leq$2% chloride ($Cl^{-}$), were presented, for temperatures slightly below room temperature and up to 355 K. In this paper, we report the thermophysical properties of mixtures of [C2mim][CH3SO3] with water, in the whole concentration range, at $P$ = 0.1 MPa. The properties measured were density and speed of sound (293.15 < $T$/K < 343.15), viscosity, electrical and thermal conductivities, refractive index (293.15 < $T$/K < 353.15), and infinite dilution diffusion coefficient of the ionic liquid in water (298.15 K).
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