Ghader Hootifard, Enayatollah Sheikhhosseini, Sayed Ali Ahmadi, Mahdieh Yahyazadehfar
{"title":"三维纳米复合材料的合成与表征--一种用于制备萘并吡喃嘧啶衍生物多芳香族化合物的高效环保型异相催化剂","authors":"Ghader Hootifard, Enayatollah Sheikhhosseini, Sayed Ali Ahmadi, Mahdieh Yahyazadehfar","doi":"10.1002/aoc.7705","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>In this study, a Fe-MOF was synthesized via a coprecipitation procedure and then used as support for stabilizing Ag ions and producing three-dimensional cluster bud Ag<sub>2</sub>O@Fe-MOF nanoflower composite (3D CB Ag<sub>2</sub>O@Fe-MOF NFC) by microwave irradiation. The synthesized 3D CB Ag<sub>2</sub>O@Fe-MOF NFC was applied as a heterogeneous nano-organocatalyst in green and new preparation of naphthopyranopyrimidines via three-component condensation of aryl aldehydes, β-naphthol, and barbituric acids in the solvent-free conditions at 100°C. Convenience, solvent-free conditions, good yield, and short reaction time make this strategy a promising candidate compared to other methods. The reusability and high efficiency of this catalyst four times without any notable loss of its activity makes this strategy attractive for large-scale eco-friendly applications.</p>\n </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"38 12","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Characterization of Three-Dimensional Nanocomposite as a Greatly Effective and Eco-Friendly Heterogeneous Catalyst for the Preparation of Naphthopyranopyrimidine Derivatives as Polyaromatic Compounds\",\"authors\":\"Ghader Hootifard, Enayatollah Sheikhhosseini, Sayed Ali Ahmadi, Mahdieh Yahyazadehfar\",\"doi\":\"10.1002/aoc.7705\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>In this study, a Fe-MOF was synthesized via a coprecipitation procedure and then used as support for stabilizing Ag ions and producing three-dimensional cluster bud Ag<sub>2</sub>O@Fe-MOF nanoflower composite (3D CB Ag<sub>2</sub>O@Fe-MOF NFC) by microwave irradiation. The synthesized 3D CB Ag<sub>2</sub>O@Fe-MOF NFC was applied as a heterogeneous nano-organocatalyst in green and new preparation of naphthopyranopyrimidines via three-component condensation of aryl aldehydes, β-naphthol, and barbituric acids in the solvent-free conditions at 100°C. Convenience, solvent-free conditions, good yield, and short reaction time make this strategy a promising candidate compared to other methods. The reusability and high efficiency of this catalyst four times without any notable loss of its activity makes this strategy attractive for large-scale eco-friendly applications.</p>\\n </div>\",\"PeriodicalId\":8344,\"journal\":{\"name\":\"Applied Organometallic Chemistry\",\"volume\":\"38 12\",\"pages\":\"\"},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2024-09-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Organometallic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/aoc.7705\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aoc.7705","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Synthesis and Characterization of Three-Dimensional Nanocomposite as a Greatly Effective and Eco-Friendly Heterogeneous Catalyst for the Preparation of Naphthopyranopyrimidine Derivatives as Polyaromatic Compounds
In this study, a Fe-MOF was synthesized via a coprecipitation procedure and then used as support for stabilizing Ag ions and producing three-dimensional cluster bud Ag2O@Fe-MOF nanoflower composite (3D CB Ag2O@Fe-MOF NFC) by microwave irradiation. The synthesized 3D CB Ag2O@Fe-MOF NFC was applied as a heterogeneous nano-organocatalyst in green and new preparation of naphthopyranopyrimidines via three-component condensation of aryl aldehydes, β-naphthol, and barbituric acids in the solvent-free conditions at 100°C. Convenience, solvent-free conditions, good yield, and short reaction time make this strategy a promising candidate compared to other methods. The reusability and high efficiency of this catalyst four times without any notable loss of its activity makes this strategy attractive for large-scale eco-friendly applications.
期刊介绍：
All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.
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