去除对乙酰氨基酚的分阶段光催化反应器:吸附和光催化的各个方面。

IF 2.5 4区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Dr. Claudia Aguilar, Mayra García, Dr. Carlos Montalvo, Francisco Anguebes, Dr. Mohamed Abatal, Dr. Julia Cerón, Dr. Rosa Cerón, Dr. Sandra Figueroa, Dr. Alejandro Ruiz, Dr. Marcela Rangel
{"title":"去除对乙酰氨基酚的分阶段光催化反应器:吸附和光催化的各个方面。","authors":"Dr. Claudia Aguilar,&nbsp;Mayra García,&nbsp;Dr. Carlos Montalvo,&nbsp;Francisco Anguebes,&nbsp;Dr. Mohamed Abatal,&nbsp;Dr. Julia Cerón,&nbsp;Dr. Rosa Cerón,&nbsp;Dr. Sandra Figueroa,&nbsp;Dr. Alejandro Ruiz,&nbsp;Dr. Marcela Rangel","doi":"10.1002/open.202400052","DOIUrl":null,"url":null,"abstract":"<p>The efficiency of a staged photocatalytic reactor prototype was evaluated on a semi-pilot scale with the removal of acetaminophen, for which anatase particles were synthesized by Sol-Gel and impregnated on rectangular plates of clay. X-ray diffraction and Energy Dispersive X-ray Fluorescence patterns show that the final composite is made up of Al<sub>2</sub>O<sub>3</sub> (14 %), SiO<sub>2</sub> (41 %), CaO (3 %) TiO<sub>2</sub> (34 %), and Fe<sub>2</sub>O<sub>3</sub> (7 %). The impregnation method favors the dispersion of Anatase on the surface of the adsorbent. TiO<sub>2</sub>-Anatase/Clay, classified as a macro-porous solid with H3-type hysteresis loops by N<sub>2</sub> physisorption. Adsorption processes are improved when using TiO<sub>2</sub>-Anatase/Clay compared to using TiO<sub>2</sub>-Anatase. The external mass transfer has a greater influence on the removal rate. The dimensionless parameters of the Biot number indicate there are no limitations due to the diffusive effect on the interior of the particle. The evaluation of the kinetic data under the Langmuir-Hinshelwood equation shows a decrease in efficiency as the initial concentration increases. The acetaminophen molecule shows destabilization in the structure of the aromatic ring with a visible decrease in the signals of this functional group evaluated by High-Performance Liquid Chromatography and Raman Spectroscopy.</p>","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":"13 10","pages":""},"PeriodicalIF":2.5000,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/open.202400052","citationCount":"0","resultStr":"{\"title\":\"The Staged Photocatalytic Reactor in the Removal of Acetaminophen: Aspects of Adsorption and Photocatalysis\",\"authors\":\"Dr. Claudia Aguilar,&nbsp;Mayra García,&nbsp;Dr. Carlos Montalvo,&nbsp;Francisco Anguebes,&nbsp;Dr. Mohamed Abatal,&nbsp;Dr. Julia Cerón,&nbsp;Dr. Rosa Cerón,&nbsp;Dr. Sandra Figueroa,&nbsp;Dr. Alejandro Ruiz,&nbsp;Dr. Marcela Rangel\",\"doi\":\"10.1002/open.202400052\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The efficiency of a staged photocatalytic reactor prototype was evaluated on a semi-pilot scale with the removal of acetaminophen, for which anatase particles were synthesized by Sol-Gel and impregnated on rectangular plates of clay. X-ray diffraction and Energy Dispersive X-ray Fluorescence patterns show that the final composite is made up of Al<sub>2</sub>O<sub>3</sub> (14 %), SiO<sub>2</sub> (41 %), CaO (3 %) TiO<sub>2</sub> (34 %), and Fe<sub>2</sub>O<sub>3</sub> (7 %). The impregnation method favors the dispersion of Anatase on the surface of the adsorbent. TiO<sub>2</sub>-Anatase/Clay, classified as a macro-porous solid with H3-type hysteresis loops by N<sub>2</sub> physisorption. Adsorption processes are improved when using TiO<sub>2</sub>-Anatase/Clay compared to using TiO<sub>2</sub>-Anatase. The external mass transfer has a greater influence on the removal rate. The dimensionless parameters of the Biot number indicate there are no limitations due to the diffusive effect on the interior of the particle. The evaluation of the kinetic data under the Langmuir-Hinshelwood equation shows a decrease in efficiency as the initial concentration increases. The acetaminophen molecule shows destabilization in the structure of the aromatic ring with a visible decrease in the signals of this functional group evaluated by High-Performance Liquid Chromatography and Raman Spectroscopy.</p>\",\"PeriodicalId\":9831,\"journal\":{\"name\":\"ChemistryOpen\",\"volume\":\"13 10\",\"pages\":\"\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2024-09-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/open.202400052\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemistryOpen\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/open.202400052\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemistryOpen","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/open.202400052","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

通过溶胶-凝胶法合成锐钛矿颗粒并将其浸渍在矩形粘土板上,在半试验规模上评估了分阶段光催化反应器原型去除对乙酰氨基酚的效率。X 射线衍射和能量色散 X 射线荧光图显示,最终的复合材料由 Al2O3(14%)、SiO2(41%)、CaO(3%)、TiO2(34%)和 Fe2O3(7%)组成。浸渍法有利于 Anatase 在吸附剂表面的分散。TiO2-Anatase/Clay,通过 N2 物理吸附被归类为具有 H3 型滞后环的大孔固体。与使用 TiO2-Anatase 相比,使用 TiO2-Anatase/Clay 可改善吸附过程。外部传质对去除率的影响更大。Biot 数的无量纲参数表明,颗粒内部的扩散效应不会造成限制。根据 Langmuir-Hinshelwood 方程对动力学数据进行的评估表明,随着初始浓度的增加,效率会降低。对乙酰氨基酚分子的芳香环结构不稳定,通过高效液相色谱法和拉曼光谱法评估,该官能团的信号明显减少。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The Staged Photocatalytic Reactor in the Removal of Acetaminophen: Aspects of Adsorption and Photocatalysis

The Staged Photocatalytic Reactor in the Removal of Acetaminophen: Aspects of Adsorption and Photocatalysis

The Staged Photocatalytic Reactor in the Removal of Acetaminophen: Aspects of Adsorption and Photocatalysis

The efficiency of a staged photocatalytic reactor prototype was evaluated on a semi-pilot scale with the removal of acetaminophen, for which anatase particles were synthesized by Sol-Gel and impregnated on rectangular plates of clay. X-ray diffraction and Energy Dispersive X-ray Fluorescence patterns show that the final composite is made up of Al2O3 (14 %), SiO2 (41 %), CaO (3 %) TiO2 (34 %), and Fe2O3 (7 %). The impregnation method favors the dispersion of Anatase on the surface of the adsorbent. TiO2-Anatase/Clay, classified as a macro-porous solid with H3-type hysteresis loops by N2 physisorption. Adsorption processes are improved when using TiO2-Anatase/Clay compared to using TiO2-Anatase. The external mass transfer has a greater influence on the removal rate. The dimensionless parameters of the Biot number indicate there are no limitations due to the diffusive effect on the interior of the particle. The evaluation of the kinetic data under the Langmuir-Hinshelwood equation shows a decrease in efficiency as the initial concentration increases. The acetaminophen molecule shows destabilization in the structure of the aromatic ring with a visible decrease in the signals of this functional group evaluated by High-Performance Liquid Chromatography and Raman Spectroscopy.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
ChemistryOpen
ChemistryOpen CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
4.80
自引率
4.30%
发文量
143
审稿时长
1 months
期刊介绍: ChemistryOpen is a multidisciplinary, gold-road open-access, international forum for the publication of outstanding Reviews, Full Papers, and Communications from all areas of chemistry and related fields. It is co-owned by 16 continental European Chemical Societies, who have banded together in the alliance called ChemPubSoc Europe for the purpose of publishing high-quality journals in the field of chemistry and its border disciplines. As some of the governments of the countries represented in ChemPubSoc Europe have strongly recommended that the research conducted with their funding is freely accessible for all readers (Open Access), ChemPubSoc Europe was concerned that no journal for which the ethical standards were monitored by a chemical society was available for such papers. ChemistryOpen fills this gap.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信