双(2-羧基喹啉)六氯化锡(IV)二水合物

IUCrData Pub Date : 2024-08-01 DOI:10.1107/S2414314624008265

Mohamed Siradj Eddine Benhamada , Tarek Benlatreche , Rochdi Ghallab , George Dénès , Hocine Merazig

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引用次数: 0

摘要

在水合标题盐 (C10H8NO2)2[SnCl6]-2H2O 中，锡（IV）原子位于一个反转中心附近。在晶体结构中，有机阳离子、八面体无机阴离子和结晶水分子通过 O-H⋯O、N-H⋯O 和 O-H⋯Cl 氢键相互作用，并辅以相邻阳离子之间微弱的 π-π 堆积和 C-Cl⋯π 相互作用：下载高清图片 (192KB)Download：下载全尺寸图像

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Bis(2-carboxyquinolinium) hexachloridostannate(IV) dihydrate

In the title compound, the 2-carboxyquinolinium cation, the [SnCl₆]^2– anion (site symmetry

) and the water molecule of crystallization are held together by hydrogen bonds, π–π stacking and C—Cl⋯π interactions.

In the hydrated title salt, (C₁₀H₈NO₂)₂[SnCl₆]·2H₂O, the tin(IV) atom is located about a center of inversion. In the crystal structure, the organic cation, the octahedral inorganic anion and the water molecule of crystallization interact through O—H⋯O, N—H⋯O and O—H⋯Cl hydrogen bonds, supplemented by weak π–π stacking between neighboring cations, and C—Cl⋯π interactions.

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IUCrData

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0.30

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