通过钯催化硫酸根阴离子与芳基噻蒽盐的芳基化反应合成氧化硫。

IF 3.3 2区化学 Q1 CHEMISTRY, ORGANIC

The Journal of Organic Chemistry Pub Date : 2024-09-20 Epub Date: 2024-09-03 DOI:10.1021/acs.joc.4c01418

Feifei Jin, Qianqian Hu, Qiang Wang, Jing Sun, Kun Huang, Chao-Guo Yan, Ying Han, Haiyang Fei, Lei Wang

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引用次数: 0

摘要

本研究展示了一种新型高效的 Pd 催化硫酸根阴离子与芳基噻蒽盐的芳基化反应。该过程提供了一种实用的方案，可在中等至较高产率下合成各种二芳基和烷基芳基硫醚。新方法的反应条件温和，底物范围广，对官能团的耐受性好。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis of Sulfoxides by Palladium-Catalyzed Arylation of Sulfenate Anions with Aryl Thianthrenium Salts.

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Synthesis of Sulfoxides by Palladium-Catalyzed Arylation of Sulfenate Anions with Aryl Thianthrenium Salts.

A novel and highly efficient Pd-catalyzed arylation of sulfenate anions with aryl thianthrenium salts is demonstrated. This procedure provides a practical protocol to synthesize various diaryl and alkyl aryl sulfoxides in moderate-to-good yields. The new approach shows mild reaction conditions, broad substrate scope, and good functional group tolerance.

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来源期刊

The Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： The Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.