用于染料工业废水修复的硒装饰氮化石墨碳纳米复合材料的光催化活性

IF 4.9 Q2 ENGINEERING, ENVIRONMENTAL
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引用次数: 0

摘要

本研究采用廉价的尿素和硒金属粉末作为前驱体材料,制备了原位硒掺杂石墨氮化碳(又称 Se-g-C3N4(SCN))。研究人员利用 SEM(扫描电子显微镜)、XRD(X 射线衍射)、FTIR(傅立叶变换红外光谱)和 TEM(透射电子显微镜)技术来描述处理后的光催化剂的形态特征、光学特征和结构特征。石墨氮化碳(g-C3N4)是一种无金属光催化剂,由于其在光催化环境污染修复中的潜在用途而受到广泛关注。这项研究不仅提供了一种提高 g-C3N4 光催化性能的直接方法,还为高效聚合物光催化剂的合理制备开辟了一条新途径。研究结果表明,这种方法不会改变样品的晶体结构,反而会通过广泛分散 g-C3N4 增加其表面积。针对亚甲基蓝(MB)和甲基橙(MO)的光降解,研究人员创建了三种不同质量比的 g-C3N4 和 SeNPs 光催化复合材料,分别为 1:1、2:1 和 3:1,并将其命名为 SCN1、SCN2 和 SCN3。在可见光(500-800 纳米)下 150 分钟后,g-C3N4 对甲基溴的综合光催化降解率为 52.4%,SCN1 为 75.4%,SCN2 为 87.8%,SCN3 为 81.3%。此外,还研究了所生产材料对甲基橙的光催化活性。分析结果显示,g-C3N4、SCN1(62.5%)、SCN2(74.1%)和 SCN3(68.5%)的劣化值分别为 45.6%、62.5%、74.1% 和 68.5%。合成的光催化剂为有效去除染料工业废水提供了巨大的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Photocatalytic activity of selenium decorated graphitic carbon nitride nanocomposites for dye Industries wastewater remediation

Photocatalytic activity of selenium decorated graphitic carbon nitride nanocomposites for dye Industries wastewater remediation

In situ selenium-doped graphitic carbon nitride, also known as Se-g-C3N4(SCN), were created in the current study by employing inexpensive urea and selenium metal powder as precursor materials. SEM (scanning electron microscopy), XRD (X-ray diffraction), FTIR (Fourier-transform infrared spectroscopy), as well as TEM (transmission electron microscopy) techniques were utilized to describe the morphological characteristics, optical characteristics, and structural characteristics of the treated photocatalyst. Because of its potential use in photocatalytic environmental pollution remediation, graphitic carbon nitride (g-C3N4), a metal-free photocatalyst, has received a lot of interest. This work not only offers a straightforward method to improve the photocatalytic performance for g-C3N4 but also creates a new path for the logical preparation of efficient polymeric photocatalysts. The results demonstrate that does not alter the crystalline structure of the sample but instead increases the surface area of g-C3N4 by dispersing it widely. Three different photocatalytic composites of g-C3N4 and SeNPs in the mass ratios of 1:1, 2:1, and 3:1, denoted SCN1, SCN2, and SCN3, were created for the methylene blue (MB) and methyl orange (MO) photodegradation. The combined photocatalytic degradation rate of MB after 150 min in visible light (500–800 nm) was 52.4% for g-C3N4, 75.4% for SCN1, 87.8% for SCN2, and 81.3% for SCN3. For methyl orange, the photocatalytic activity of produced materials was also investigated. The analysis's outcome reveals astonishing deterioration values were 45.6% for g-C3N4, SCN1 (62.5%), SCN2 (74.1%), and SCN3(68.5%), respectively. The synthesized photocatalyst offers great potential for the effective removal of dye industeries wastewater remediation.

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来源期刊
Groundwater for Sustainable Development
Groundwater for Sustainable Development Social Sciences-Geography, Planning and Development
CiteScore
11.50
自引率
10.20%
发文量
152
期刊介绍: Groundwater for Sustainable Development is directed to different stakeholders and professionals, including government and non-governmental organizations, international funding agencies, universities, public water institutions, public health and other public/private sector professionals, and other relevant institutions. It is aimed at professionals, academics and students in the fields of disciplines such as: groundwater and its connection to surface hydrology and environment, soil sciences, engineering, ecology, microbiology, atmospheric sciences, analytical chemistry, hydro-engineering, water technology, environmental ethics, economics, public health, policy, as well as social sciences, legal disciplines, or any other area connected with water issues. The objectives of this journal are to facilitate: • The improvement of effective and sustainable management of water resources across the globe. • The improvement of human access to groundwater resources in adequate quantity and good quality. • The meeting of the increasing demand for drinking and irrigation water needed for food security to contribute to a social and economically sound human development. • The creation of a global inter- and multidisciplinary platform and forum to improve our understanding of groundwater resources and to advocate their effective and sustainable management and protection against contamination. • Interdisciplinary information exchange and to stimulate scientific research in the fields of groundwater related sciences and social and health sciences required to achieve the United Nations Millennium Development Goals for sustainable development.
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