{"title":"受珍珠质启发的超韧阻燃还原氧化石墨烯复合薄膜","authors":"","doi":"10.1016/j.coco.2024.102043","DOIUrl":null,"url":null,"abstract":"<div><p>Nacre-like graphene composite films (GCFs) with high strength have been highly developed. However, the GCFs usually exhibit relatively poor toughness and poor flame resistance, seriously limiting their applications as structural materials. Here, reduced graphene oxide (rGO), halloysite nanotubes (HNTs), and flame-retarding modified lignin (F-lignin) were compounded to fabricate the rGO-HNTs-(F-lignin) film. In the rGO-HNTs-(F-lignin) film, the F-lignin binds the rGO sheets and HNTs, enhancing the entanglement of HNTs and the interactions between HNTs and rGO sheets, and the macromolecular F-lignin also improves the ductility of the rGO-HNTs-(F-lignin) film, while the entangled HNTs conversely reinforce the F-lignin to prevent the F-lignin from fracture when the rGO-HNTs-(F-lignin) film is under stress, further increasing the ductility of the rGO-HNTs-(F-lignin) film. The HNTs and F-lignin promote each other to enhance the strengthening and toughening effect on the rGO-HNTs-(F-lignin)-film, and endowing the rGO-HNTs-(F-lignin)-film with the superior mechanical properties of the tensile strength of 634 ± 38 MPa, tensile fracture strain of 8.17 ± 0.59 %, and toughness of 25.35 ± 2.95 MJ/m<sup>3</sup>, respectively. The rGO-HNTs-(F-lignin) film also exhibits improved flame-retardant properties due to the high flame retardancy of HNTs and F-lignin. These excellent integrated properties of the rGO-HNTs-(F-lignin) film will promote its potential applications as structural materials.</p></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":null,"pages":null},"PeriodicalIF":6.5000,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Nacre inspired supertough and flame-retardant reduced graphene oxide composite films\",\"authors\":\"\",\"doi\":\"10.1016/j.coco.2024.102043\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Nacre-like graphene composite films (GCFs) with high strength have been highly developed. However, the GCFs usually exhibit relatively poor toughness and poor flame resistance, seriously limiting their applications as structural materials. Here, reduced graphene oxide (rGO), halloysite nanotubes (HNTs), and flame-retarding modified lignin (F-lignin) were compounded to fabricate the rGO-HNTs-(F-lignin) film. In the rGO-HNTs-(F-lignin) film, the F-lignin binds the rGO sheets and HNTs, enhancing the entanglement of HNTs and the interactions between HNTs and rGO sheets, and the macromolecular F-lignin also improves the ductility of the rGO-HNTs-(F-lignin) film, while the entangled HNTs conversely reinforce the F-lignin to prevent the F-lignin from fracture when the rGO-HNTs-(F-lignin) film is under stress, further increasing the ductility of the rGO-HNTs-(F-lignin) film. The HNTs and F-lignin promote each other to enhance the strengthening and toughening effect on the rGO-HNTs-(F-lignin)-film, and endowing the rGO-HNTs-(F-lignin)-film with the superior mechanical properties of the tensile strength of 634 ± 38 MPa, tensile fracture strain of 8.17 ± 0.59 %, and toughness of 25.35 ± 2.95 MJ/m<sup>3</sup>, respectively. The rGO-HNTs-(F-lignin) film also exhibits improved flame-retardant properties due to the high flame retardancy of HNTs and F-lignin. These excellent integrated properties of the rGO-HNTs-(F-lignin) film will promote its potential applications as structural materials.</p></div>\",\"PeriodicalId\":10533,\"journal\":{\"name\":\"Composites Communications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.5000,\"publicationDate\":\"2024-08-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Composites Communications\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2452213924002341\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Composites Communications","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2452213924002341","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
Nacre inspired supertough and flame-retardant reduced graphene oxide composite films
Nacre-like graphene composite films (GCFs) with high strength have been highly developed. However, the GCFs usually exhibit relatively poor toughness and poor flame resistance, seriously limiting their applications as structural materials. Here, reduced graphene oxide (rGO), halloysite nanotubes (HNTs), and flame-retarding modified lignin (F-lignin) were compounded to fabricate the rGO-HNTs-(F-lignin) film. In the rGO-HNTs-(F-lignin) film, the F-lignin binds the rGO sheets and HNTs, enhancing the entanglement of HNTs and the interactions between HNTs and rGO sheets, and the macromolecular F-lignin also improves the ductility of the rGO-HNTs-(F-lignin) film, while the entangled HNTs conversely reinforce the F-lignin to prevent the F-lignin from fracture when the rGO-HNTs-(F-lignin) film is under stress, further increasing the ductility of the rGO-HNTs-(F-lignin) film. The HNTs and F-lignin promote each other to enhance the strengthening and toughening effect on the rGO-HNTs-(F-lignin)-film, and endowing the rGO-HNTs-(F-lignin)-film with the superior mechanical properties of the tensile strength of 634 ± 38 MPa, tensile fracture strain of 8.17 ± 0.59 %, and toughness of 25.35 ± 2.95 MJ/m3, respectively. The rGO-HNTs-(F-lignin) film also exhibits improved flame-retardant properties due to the high flame retardancy of HNTs and F-lignin. These excellent integrated properties of the rGO-HNTs-(F-lignin) film will promote its potential applications as structural materials.
期刊介绍:
Composites Communications (Compos. Commun.) is a peer-reviewed journal publishing short communications and letters on the latest advances in composites science and technology. With a rapid review and publication process, its goal is to disseminate new knowledge promptly within the composites community. The journal welcomes manuscripts presenting creative concepts and new findings in design, state-of-the-art approaches in processing, synthesis, characterization, and mechanics modeling. In addition to traditional fiber-/particulate-reinforced engineering composites, it encourages submissions on composites with exceptional physical, mechanical, and fracture properties, as well as those with unique functions and significant application potential. This includes biomimetic and bio-inspired composites for biomedical applications, functional nano-composites for thermal management and energy applications, and composites designed for extreme service environments.