光活性孔雀石绿基炔基铂（II）2,6-双（N-烷基苯并咪唑-2-基）吡啶配合物。

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2024-09-24 DOI:10.1039/d4cc03558e

Andy Shun-Hoi Cheung, Ming-Yi Leung, Tony Ho-Ching Fung, Vivian Wing-Wah Yam

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引用次数: 0

摘要

一种炔基铂(II)偶联体系中加入了光响应孔雀石绿分子。光笼络物在乙腈溶液中表现出自组装特性，可通过光去除氰基保护基团进行调节。在光照射前后，可以观察到不同的聚合形态，这些形态是由非共价的金属-金属和 π-π 堆积相互作用促成的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Photoactivable malachite green-based alkynylplatinum(II) 2,6-bis(N-alkylbenzimidazol-2-yl)pyridine complexes.

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Photoactivable malachite green-based alkynylplatinum(II) 2,6-bis(N-alkylbenzimidazol-2-yl)pyridine complexes.

Photo-responsive malachite green moieties have been incorporated into an alkynylplatinum(II) bzimpy system. The photo-caged complexes in acetonitrile solutions exhibit self-assembly properties modulable by photo-removal of the cyano protecting group. Distinct aggregate morphologies, which are facilitated by the non-covalent metal-metal and π-π stacking interactions, have been observed before and after photo-irradiation.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.