{"title":"基于 N2、H2O 和 CO2 气体等温线的微观结构分析以及利用 X 射线 CT 对添加石墨的挤塑聚苯乙烯泡沫进行三维成像","authors":"Yoobin Leem, Ryoma Kitagaki, Daishi Takahashi, Wataru Kaneshika","doi":"10.1002/masy.202300241","DOIUrl":null,"url":null,"abstract":"<p>A type of foamed plastic insulation that improves thermal performance while maintaining the original durability by adding fillers with low radiation rates in foamed plastic insulation is investigated. The thermal conductivity of extruded polystyrene foam (XPS) adding graphite is reduced by 14% compared to without graphite additives. The study investigates that mechanism by comparing the properties of XPS and XPS containing graphite (graph XPS) through the gas isotherm method and 3D imaging analysis by X-ray CT. First, the specific surface area of the insulation's resin is examined through the gas isotherm method using N2, H<sub>2</sub>O, and CO<sub>2</sub>. The results confirmed that graph XPS has a more increased specific surface area than XPS. Second, the internal structure of the insulation and its strut/pore distribution is confirmed through X-ray CT, which showed an increase in surface area with a thinning of the strut. The improved thermal performance due to the addition of graphite may contribute to an increase in the surface area of the insulation.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"413 4","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microstructure Analysis Based on Gas Isotherms of N2, H2O and CO2 and 3D Imaging Using X-Ray CT into Extruded Polystyrene foam Adding Graphite\",\"authors\":\"Yoobin Leem, Ryoma Kitagaki, Daishi Takahashi, Wataru Kaneshika\",\"doi\":\"10.1002/masy.202300241\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A type of foamed plastic insulation that improves thermal performance while maintaining the original durability by adding fillers with low radiation rates in foamed plastic insulation is investigated. The thermal conductivity of extruded polystyrene foam (XPS) adding graphite is reduced by 14% compared to without graphite additives. The study investigates that mechanism by comparing the properties of XPS and XPS containing graphite (graph XPS) through the gas isotherm method and 3D imaging analysis by X-ray CT. First, the specific surface area of the insulation's resin is examined through the gas isotherm method using N2, H<sub>2</sub>O, and CO<sub>2</sub>. The results confirmed that graph XPS has a more increased specific surface area than XPS. Second, the internal structure of the insulation and its strut/pore distribution is confirmed through X-ray CT, which showed an increase in surface area with a thinning of the strut. The improved thermal performance due to the addition of graphite may contribute to an increase in the surface area of the insulation.</p>\",\"PeriodicalId\":18107,\"journal\":{\"name\":\"Macromolecular Symposia\",\"volume\":\"413 4\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-08-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecular Symposia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/masy.202300241\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Materials Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Symposia","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/masy.202300241","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Materials Science","Score":null,"Total":0}
引用次数: 0
摘要
通过在发泡塑料隔热材料中添加辐射率低的填料,研究了一种既能提高隔热性能,又能保持原有耐用性的发泡塑料隔热材料。与不添加石墨的挤塑聚苯乙烯泡沫(XPS)相比,添加石墨的挤塑聚苯乙烯泡沫的导热性降低了 14%。本研究通过气体等温线法和 X 射线 CT 三维成像分析,比较了 XPS 和含有石墨的 XPS(图形 XPS)的特性,从而研究了这一机理。首先,通过使用 N2、H2O 和 CO2 的气体等温线法检测绝缘树脂的比表面积。结果证实,图形 XPS 比 XPS 的比表面积更大。其次,通过 X 射线 CT 确认了隔热材料的内部结构及其支柱/孔隙分布,结果表明随着支柱变薄,表面积也随之增大。由于添加了石墨,隔热性能得到改善,这可能有助于增加隔热材料的表面积。
Microstructure Analysis Based on Gas Isotherms of N2, H2O and CO2 and 3D Imaging Using X-Ray CT into Extruded Polystyrene foam Adding Graphite
A type of foamed plastic insulation that improves thermal performance while maintaining the original durability by adding fillers with low radiation rates in foamed plastic insulation is investigated. The thermal conductivity of extruded polystyrene foam (XPS) adding graphite is reduced by 14% compared to without graphite additives. The study investigates that mechanism by comparing the properties of XPS and XPS containing graphite (graph XPS) through the gas isotherm method and 3D imaging analysis by X-ray CT. First, the specific surface area of the insulation's resin is examined through the gas isotherm method using N2, H2O, and CO2. The results confirmed that graph XPS has a more increased specific surface area than XPS. Second, the internal structure of the insulation and its strut/pore distribution is confirmed through X-ray CT, which showed an increase in surface area with a thinning of the strut. The improved thermal performance due to the addition of graphite may contribute to an increase in the surface area of the insulation.
期刊介绍:
Macromolecular Symposia presents state-of-the-art research articles in the field of macromolecular chemistry and physics. All submitted contributions are peer-reviewed to ensure a high quality of published manuscripts. Accepted articles will be typeset and published as a hardcover edition together with online publication at Wiley InterScience, thereby guaranteeing an immediate international dissemination.