Chijioke Peter Egole , Gaius Chukwuka Nzebuka , Chukwuzubelu Okenwa Ufodike , Rasaq Olawale Medupin , Chima Chinedu Ugwuegbu , Nnamdi Anthony Nnodum , Ugochukwu Philip Ochieze
{"title":"两种与长石和石英混合的粘土沉积物在建筑服务和耐火材料应用中的实验特性分析","authors":"Chijioke Peter Egole , Gaius Chukwuka Nzebuka , Chukwuzubelu Okenwa Ufodike , Rasaq Olawale Medupin , Chima Chinedu Ugwuegbu , Nnamdi Anthony Nnodum , Ugochukwu Philip Ochieze","doi":"10.1016/j.jafrearsci.2024.105373","DOIUrl":null,"url":null,"abstract":"<div><p>Clay deposits across the globe have variations in mineralogical compositions that elicit their use in numerous applications. In this study, two clay deposits were identified and blended with feldspar and quartz in various amounts to produce different samples of composites that could be used for applications in building services and refractories. Chemical analysis, mineralogical composition, microstructure, physical properties, and thermal behaviours were characterized. The X-ray fluorescence <strong>(</strong>XRF) analysis results show that the clays belong to the aluminosilicate group containing traces of other oxides which enhance strength and the crystallization of thermally stable phases. The XRD patterns confirmed the presence of dominant quartz with moderate to minor presence of kaolin, orthoclase, and albite. The texture of the clays showed particles of different sizes and shapes with uneven distribution. The EDX characteristic spectrum showed x-ray characteristic peaks of Si, Al, Fe, K, and O which affirmed their major oxide compositions. Physical properties results show that firing at various temperatures and blending resulted to increase in Bulk density and flexural strength while apparent porosity and water absorption decreased. The TGA, DTA, and DSC results show that the two clay minerals are thermally stable. This can be attributed to the nucleation and crystallization of refractory phases like cristobalite and mullite. Addition of feldspar and quartz was found to contribute significantly to improve the overall properties of the investigated clays. A comparison of the various results from the two clay deposits suggests that they could be suitable for building services and refractory applications.</p></div>","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":"218 ","pages":"Article 105373"},"PeriodicalIF":2.2000,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Experimental characterization of two clay deposits blended with feldspar and quartz for building services and refractory applications\",\"authors\":\"Chijioke Peter Egole , Gaius Chukwuka Nzebuka , Chukwuzubelu Okenwa Ufodike , Rasaq Olawale Medupin , Chima Chinedu Ugwuegbu , Nnamdi Anthony Nnodum , Ugochukwu Philip Ochieze\",\"doi\":\"10.1016/j.jafrearsci.2024.105373\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Clay deposits across the globe have variations in mineralogical compositions that elicit their use in numerous applications. In this study, two clay deposits were identified and blended with feldspar and quartz in various amounts to produce different samples of composites that could be used for applications in building services and refractories. Chemical analysis, mineralogical composition, microstructure, physical properties, and thermal behaviours were characterized. The X-ray fluorescence <strong>(</strong>XRF) analysis results show that the clays belong to the aluminosilicate group containing traces of other oxides which enhance strength and the crystallization of thermally stable phases. The XRD patterns confirmed the presence of dominant quartz with moderate to minor presence of kaolin, orthoclase, and albite. The texture of the clays showed particles of different sizes and shapes with uneven distribution. The EDX characteristic spectrum showed x-ray characteristic peaks of Si, Al, Fe, K, and O which affirmed their major oxide compositions. Physical properties results show that firing at various temperatures and blending resulted to increase in Bulk density and flexural strength while apparent porosity and water absorption decreased. The TGA, DTA, and DSC results show that the two clay minerals are thermally stable. This can be attributed to the nucleation and crystallization of refractory phases like cristobalite and mullite. Addition of feldspar and quartz was found to contribute significantly to improve the overall properties of the investigated clays. A comparison of the various results from the two clay deposits suggests that they could be suitable for building services and refractory applications.</p></div>\",\"PeriodicalId\":14874,\"journal\":{\"name\":\"Journal of African Earth Sciences\",\"volume\":\"218 \",\"pages\":\"Article 105373\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-08-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of African Earth Sciences\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1464343X24002061\",\"RegionNum\":4,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"GEOSCIENCES, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of African Earth Sciences","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1464343X24002061","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
Experimental characterization of two clay deposits blended with feldspar and quartz for building services and refractory applications
Clay deposits across the globe have variations in mineralogical compositions that elicit their use in numerous applications. In this study, two clay deposits were identified and blended with feldspar and quartz in various amounts to produce different samples of composites that could be used for applications in building services and refractories. Chemical analysis, mineralogical composition, microstructure, physical properties, and thermal behaviours were characterized. The X-ray fluorescence (XRF) analysis results show that the clays belong to the aluminosilicate group containing traces of other oxides which enhance strength and the crystallization of thermally stable phases. The XRD patterns confirmed the presence of dominant quartz with moderate to minor presence of kaolin, orthoclase, and albite. The texture of the clays showed particles of different sizes and shapes with uneven distribution. The EDX characteristic spectrum showed x-ray characteristic peaks of Si, Al, Fe, K, and O which affirmed their major oxide compositions. Physical properties results show that firing at various temperatures and blending resulted to increase in Bulk density and flexural strength while apparent porosity and water absorption decreased. The TGA, DTA, and DSC results show that the two clay minerals are thermally stable. This can be attributed to the nucleation and crystallization of refractory phases like cristobalite and mullite. Addition of feldspar and quartz was found to contribute significantly to improve the overall properties of the investigated clays. A comparison of the various results from the two clay deposits suggests that they could be suitable for building services and refractory applications.
期刊介绍:
The Journal of African Earth Sciences sees itself as the prime geological journal for all aspects of the Earth Sciences about the African plate. Papers dealing with peripheral areas are welcome if they demonstrate a tight link with Africa.
The Journal publishes high quality, peer-reviewed scientific papers. It is devoted primarily to research papers but short communications relating to new developments of broad interest, reviews and book reviews will also be considered. Papers must have international appeal and should present work of more regional than local significance and dealing with well identified and justified scientific questions. Specialised technical papers, analytical or exploration reports must be avoided. Papers on applied geology should preferably be linked to such core disciplines and must be addressed to a more general geoscientific audience.