封面图片:揭示基于 Na4Fe3(PO4)2P2O7 阴极和硬碳阳极的钠离子电池的降解机制,建议减小阳极颗粒尺寸以提高循环稳定性(《电池与超级电容器》,8/2024)

IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY
Shubham Lochab, Sagar Bharathraj, K. Subramanya Mayya, Prabeer Barpanda, Shashishekar P. Adiga
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引用次数: 0

摘要

封面特写展示的是钠离子电池--由于钠在地球上的大量存在,它成为锂离子电池的替代品。与锂电池不同,钠离子电池的材料来源无需担心地缘政治问题。然而,它们的发展却一直受制于较差的生命周期。电化学分析、材料表征和建模找出了容量衰减的根本原因:缓慢的钠扩散会引发阳极过电位和阴极材料损耗。缩小阳极颗粒尺寸可提高容量和寿命。凭借具有成本效益的材料和简化的工艺,钠离子电池有望成为满足固定存储需求的令人信服的解决方案。更多信息,请参阅 S. P. Adiga 及其合作者的研究文章(英文版)。Adiga 及其合作者的研究文章中(DOI: 10.1002/batt.202400025)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Cover Picture: Unveiling the Degradation Mechanism of Sodium Ion Batteries Based on Na4Fe3(PO4)2P2O7 Cathode and Hard Carbon Anode Suggests Anode Particle Size Reduction for Cycling Stability (Batteries & Supercaps 8/2024)

Cover Picture: Unveiling the Degradation Mechanism of Sodium Ion Batteries Based on Na4Fe3(PO4)2P2O7 Cathode and Hard Carbon Anode Suggests Anode Particle Size Reduction for Cycling Stability (Batteries & Supercaps 8/2024)

The Cover Feature shows sodium-ion batteries—a compelling alternative to lithium-ion counterparts due to sodium‘s abundant presence on Earth. Unlike lithium, their materials can be sourced without geopolitical concerns. Yet, their advance has been hindered by a poor life cycle. Electrochemical analysis, materials characterization and modeling pinpointed the root cause of capacity decay: sluggish sodium diffusion triggers anode overpotential and cathode material loss. Shrinking anode particle size enhances both capacity and longevity. With cost-effective materials and streamlined processes, sodium-ion batteries promise a compelling solution for stationary storage needs. More information can be found in the Research Article by S. P. Adiga and co-workers (DOI: 10.1002/batt.202400025).

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来源期刊
CiteScore
8.60
自引率
5.30%
发文量
223
期刊介绍: Electrochemical energy storage devices play a transformative role in our societies. They have allowed the emergence of portable electronics devices, have triggered the resurgence of electric transportation and constitute key components in smart power grids. Batteries & Supercaps publishes international high-impact experimental and theoretical research on the fundamentals and applications of electrochemical energy storage. We support the scientific community to advance energy efficiency and sustainability.
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