前言:通过杂金属一维链中 13 Å 金属间距的反铁磁相互作用

Prof. Dr. Kazuhiro Uemura, Tomonori Adachi, Dr. Atsushi Takamori, Prof. Dr. Michiyuki Yoshida
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引用次数: 0

摘要

杂金属配合物。在他们的通讯(e202408415)中,Kazuhiro Uemura 合成了一种具有异金属键的顺磁链-Rh-Rh-Pt-Ni-Pt-。镍原子上的未成对电子通过金属-金属键产生强烈的反铁磁相互作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Frontispiz: Antiferromagnetic Interactions through the Thirteen Å Metal–Metal Distances in Heterometallic One-Dimensional Chains

Frontispiz: Antiferromagnetic Interactions through the Thirteen Å Metal–Metal Distances in Heterometallic One-Dimensional Chains

Heterometallic Complexes. In their Communication (e202408415), Kazuhiro Uemura synthesized a paramagnetic chain aligned as –Rh–Rh–Pt–Ni–Pt– with heterometallic bonds. The unpaired electrons on the Ni atoms strongly interact antiferromagnetically through metal–metal bonds.

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来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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