Kirill G. Pavlov , Dmitry A. Guk , Roman O. Burlutsky , Anna A. Moiseeva , Olga O. Krasnovskaya , Dmitry A. Lemenovskiy , Nikolay V. Zyk , Elena K. Beloglazkina
{"title":"BODIPY 乙炔和二茂铁叠氮化物在超临界二氧化碳中的 Huisgen 环加成反应","authors":"Kirill G. Pavlov , Dmitry A. Guk , Roman O. Burlutsky , Anna A. Moiseeva , Olga O. Krasnovskaya , Dmitry A. Lemenovskiy , Nikolay V. Zyk , Elena K. Beloglazkina","doi":"10.1016/j.mencom.2024.06.027","DOIUrl":null,"url":null,"abstract":"<div><p>The copper-catalyzed azide–alkyne cycloaddition of BODIPY acetylene derivative and ferrocene azides in supercritical CO<sub>2</sub> at 80 °C and 81 bar affords the corresponding triazole-containing BODIPY–ferrocene conjugates in high yields. The fluorescent and electrochemical properties of the compounds thus obtained were explored.</p></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Huisgen’s cycloaddition of BODIPY acetylene and ferrocene azides in supercritical CO2\",\"authors\":\"Kirill G. Pavlov , Dmitry A. Guk , Roman O. Burlutsky , Anna A. Moiseeva , Olga O. Krasnovskaya , Dmitry A. Lemenovskiy , Nikolay V. Zyk , Elena K. Beloglazkina\",\"doi\":\"10.1016/j.mencom.2024.06.027\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The copper-catalyzed azide–alkyne cycloaddition of BODIPY acetylene derivative and ferrocene azides in supercritical CO<sub>2</sub> at 80 °C and 81 bar affords the corresponding triazole-containing BODIPY–ferrocene conjugates in high yields. The fluorescent and electrochemical properties of the compounds thus obtained were explored.</p></div>\",\"PeriodicalId\":18542,\"journal\":{\"name\":\"Mendeleev Communications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Mendeleev Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0959943624002049\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Mendeleev Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0959943624002049","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
在 80 °C 和 81 bar 的超临界 CO2 条件下,铜催化叠氮-炔环化反应生成了相应的含三唑的 BODIPY-二茂铁共轭物。研究人员对由此获得的化合物的荧光和电化学特性进行了探讨。
The Huisgen’s cycloaddition of BODIPY acetylene and ferrocene azides in supercritical CO2
The copper-catalyzed azide–alkyne cycloaddition of BODIPY acetylene derivative and ferrocene azides in supercritical CO2 at 80 °C and 81 bar affords the corresponding triazole-containing BODIPY–ferrocene conjugates in high yields. The fluorescent and electrochemical properties of the compounds thus obtained were explored.
期刊介绍:
Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications.
Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.