{"title":"在多孔单晶聚合物支撑的钯催化剂上进行烯烃的马尔科夫尼科夫选择性加氢氨基羰基化反应","authors":"","doi":"10.1039/d4cy00742e","DOIUrl":null,"url":null,"abstract":"<div><p>Here we develop a porous monophoshine polymer supported Pd catalyst (Pd/POL-<em>m</em>-3vPPh<sub>3</sub>) for hydroaminocarbonylation of aromatic alkenes with amines, showing excellent catalytic activity (up to 97% yield) and Markovnikov selectivity (up to 99%) for producing branched amides. This catalyst exhibits broad substrate compatibility, and is reused for two times with no significant decline in the performance and three times with no significant Pd leaching, as well as applied for the synthesis of naproxen.</p></div>","PeriodicalId":66,"journal":{"name":"Catalysis Science & Technology","volume":null,"pages":null},"PeriodicalIF":4.4000,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Markovnikov selective hydroaminocarbonylation of alkenes over a porous monophoshine polymer supported palladium catalyst†\",\"authors\":\"\",\"doi\":\"10.1039/d4cy00742e\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Here we develop a porous monophoshine polymer supported Pd catalyst (Pd/POL-<em>m</em>-3vPPh<sub>3</sub>) for hydroaminocarbonylation of aromatic alkenes with amines, showing excellent catalytic activity (up to 97% yield) and Markovnikov selectivity (up to 99%) for producing branched amides. This catalyst exhibits broad substrate compatibility, and is reused for two times with no significant decline in the performance and three times with no significant Pd leaching, as well as applied for the synthesis of naproxen.</p></div>\",\"PeriodicalId\":66,\"journal\":{\"name\":\"Catalysis Science & Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2024-08-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Science & Technology\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2044475324004301\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Science & Technology","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2044475324004301","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Markovnikov selective hydroaminocarbonylation of alkenes over a porous monophoshine polymer supported palladium catalyst†
Here we develop a porous monophoshine polymer supported Pd catalyst (Pd/POL-m-3vPPh3) for hydroaminocarbonylation of aromatic alkenes with amines, showing excellent catalytic activity (up to 97% yield) and Markovnikov selectivity (up to 99%) for producing branched amides. This catalyst exhibits broad substrate compatibility, and is reused for two times with no significant decline in the performance and three times with no significant Pd leaching, as well as applied for the synthesis of naproxen.
期刊介绍:
A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis.
Editor-in-chief: Bert Weckhuysen
Impact factor: 5.0
Time to first decision (peer reviewed only): 31 days