协同增强 Cu2O/TiO2@Ti3C2Tx MXene 三元复合材料的光催化性能

IF 2.8 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Jing Fang, Tianxiang Xu, Lidan Tan, Hui Zhu, Xuanke Li, Ye Cong
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引用次数: 0

摘要

水污染一直是人类社会发展过程中无法回避的挑战。光催化技术被认为是一种前景广阔的水污染控制策略。本研究构建了一种新型的 Cu2O/TiO2@Ti3C2Tx MXene 光催化剂,创造了多样化的电子传输途径,从而促进了电荷分离,实现了优异的光催化性能。复合光催化材料的协同效应有助于在可见光下降解有机染料。Cu2O 与原位生成的 TiO2 之间异质结结构的成功构建减轻了分离后的电荷重组,显著延长了光生载流子的寿命。此外,Ti3C2Tx 的加入可作为一种有效的导电介质,促进光生电荷在材料内部的分离和转移。因此,Cu2O/TiO2@Ti3C2Tx MXene 复合材料表现出卓越的光催化活性,在可见光照射 3 小时后,降解率达到 71.5%,表现最佳。这些发现强调了这种新化合物在增强光催化有机物降解方面的潜力,凸显了光催化材料的广阔应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synergistic enhancement of photocatalytic properties in ternary Cu2O/TiO2@Ti3C2Tx MXene composites

Synergistic enhancement of photocatalytic properties in ternary Cu2O/TiO2@Ti3C2Tx MXene composites

Water pollution has always been an inescapable challenge in the development of human society. Photocatalytic technology is regarded as a promising strategy for water pollution control. In this work, a novel Cu2O/TiO2@Ti3C2Tx MXene photocatalyst is constructed to create diverse electron transport pathways, thereby promoting charge separation and achieving superior photocatalytic performance. The synergistic effects of composite photocatalytic materials are instrumental in degrading organic dyes under visible light. The successful construction of a heterojunction structure between Cu2O and in situ generated TiO2 mitigates charge recombination post-separation, significantly extending the lifetime of photogenerated carriers. Additionally, the incorporation of Ti3C2Tx serves as an effective conductive medium, facilitating the separation and transfer of photogenerated charges within the material. Therefore, the Cu2O/TiO2@Ti3C2Tx MXene composites exhibit exceptional photocatalytic activity, showcasing the best performance, achieving a degradation rate of 71.5% after 3 h of visible light irradiation. These findings underscore the potential of this new compound in enhancing photocatalytic organic degradation, highlighting the promising application prospects of photocatalytic materials.

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来源期刊
CiteScore
5.70
自引率
18.20%
发文量
229
审稿时长
2.6 months
期刊介绍: Research on Chemical Intermediates publishes current research articles and concise dynamic reviews on the properties, structures and reactivities of intermediate species in all the various domains of chemistry. The journal also contains articles in related disciplines such as spectroscopy, molecular biology and biochemistry, atmospheric and environmental sciences, catalysis, photochemistry and photophysics. In addition, special issues dedicated to specific topics in the field are regularly published.
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