Colossal in-plane optical anisotropy in a two-dimensional van der Waals crystal

Polarization, a fundamental property of light, has been widely exploited from quantum physics to high-dimensional optics. Materials with intrinsic optical anisotropy, such as dichroism and birefringence, are central to light polarization control, including the development of polarizers, waveplates, mirrors and phase-matching elements. Therefore, materials with strong optical anisotropy have been long-sought. Recently, two-dimensional van der Waals crystals show high optical anisotropy but are mostly restricted to the out-of-plane direction, which is challenging to access in optical engineering. Here we report a two-dimensional van der Waals material, NbOCl2, that exhibits sharp electronic and structural contrast between its in-plane orthogonal axes. Colossal in-plane optical anisotropy—linear dichroism (up to 99% in ultraviolet) and birefringence (0.26–0.46 within a wide visible–near-infrared transparency window)—is experimentally demonstrated. Our findings provide a powerful and easy-to-access recipe for ultracompact integrated polarization industries. A two-dimensional van der Waals material, NbOCl2, that simultaneously exhibits near-unity linear dichroism (~99%) over 100 nm bandwidth in ultraviolet regime and large birefringence (0.26–0.46) within a wide visible–near-infrared transparency window is reported.