{"title":"用于固态照明的新型 Eu3+ 掺杂 Na2LiAlF6 氟铝酸盐的光谱研究","authors":"Sanket J. Helode , G.D. Zade , S.J. Dhoble","doi":"10.1016/j.chphi.2024.100688","DOIUrl":null,"url":null,"abstract":"<div><p>Red-emitting phosphors are crucial for sustainable white-light-emitting diodes (WLEDs) used in lighting. These materials significantly enhance the lighting and backlit display quality of phosphor-converted white LEDs (pc-WLEDs) by overcoming red deficiency. Luminescent properties of rare earth activated fluoride based inorganic compounds are most investigated due to its excellent spectral characteristics. In this paper we report the novel Na<sub>2</sub>LiAlF<sub>6</sub> luminescent host material activated with Eu<sup>3+</sup> rare earth ions synthesized by wet chemical method. The spectral analysis revels the excitation spanning in near UV region while emission spectra depict characteristic peaks transitioned in accordance with <sup>5</sup>D<sub>0</sub> to <sup>7</sup>F<sub>1</sub> and <sup>7</sup>F<sub>2</sub>. Effect of concentration quenching, Color purity and temperature studied briefly which demonstrates that the prepared red emitting phosphor is useful in various device applications such as phosphor converted White light emitting diodes for fulfilment of red deficiency, solid state lighting, display technology as an essential red component.</p></div>","PeriodicalId":9758,"journal":{"name":"Chemical Physics Impact","volume":"9 ","pages":"Article 100688"},"PeriodicalIF":3.8000,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667022424002329/pdfft?md5=e49b857b02e26258212e75d73e051f23&pid=1-s2.0-S2667022424002329-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Spectroscopic investigation of novel Eu3+ doped Na2LiAlF6 fluoroaluminate for solid state lighting applications\",\"authors\":\"Sanket J. Helode , G.D. Zade , S.J. Dhoble\",\"doi\":\"10.1016/j.chphi.2024.100688\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Red-emitting phosphors are crucial for sustainable white-light-emitting diodes (WLEDs) used in lighting. These materials significantly enhance the lighting and backlit display quality of phosphor-converted white LEDs (pc-WLEDs) by overcoming red deficiency. Luminescent properties of rare earth activated fluoride based inorganic compounds are most investigated due to its excellent spectral characteristics. In this paper we report the novel Na<sub>2</sub>LiAlF<sub>6</sub> luminescent host material activated with Eu<sup>3+</sup> rare earth ions synthesized by wet chemical method. The spectral analysis revels the excitation spanning in near UV region while emission spectra depict characteristic peaks transitioned in accordance with <sup>5</sup>D<sub>0</sub> to <sup>7</sup>F<sub>1</sub> and <sup>7</sup>F<sub>2</sub>. Effect of concentration quenching, Color purity and temperature studied briefly which demonstrates that the prepared red emitting phosphor is useful in various device applications such as phosphor converted White light emitting diodes for fulfilment of red deficiency, solid state lighting, display technology as an essential red component.</p></div>\",\"PeriodicalId\":9758,\"journal\":{\"name\":\"Chemical Physics Impact\",\"volume\":\"9 \",\"pages\":\"Article 100688\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2024-07-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2667022424002329/pdfft?md5=e49b857b02e26258212e75d73e051f23&pid=1-s2.0-S2667022424002329-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Physics Impact\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2667022424002329\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Physics Impact","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2667022424002329","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Spectroscopic investigation of novel Eu3+ doped Na2LiAlF6 fluoroaluminate for solid state lighting applications
Red-emitting phosphors are crucial for sustainable white-light-emitting diodes (WLEDs) used in lighting. These materials significantly enhance the lighting and backlit display quality of phosphor-converted white LEDs (pc-WLEDs) by overcoming red deficiency. Luminescent properties of rare earth activated fluoride based inorganic compounds are most investigated due to its excellent spectral characteristics. In this paper we report the novel Na2LiAlF6 luminescent host material activated with Eu3+ rare earth ions synthesized by wet chemical method. The spectral analysis revels the excitation spanning in near UV region while emission spectra depict characteristic peaks transitioned in accordance with 5D0 to 7F1 and 7F2. Effect of concentration quenching, Color purity and temperature studied briefly which demonstrates that the prepared red emitting phosphor is useful in various device applications such as phosphor converted White light emitting diodes for fulfilment of red deficiency, solid state lighting, display technology as an essential red component.