用 ClO2-VO(acac)2 系统氧化取代的苯酚

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2024-07-26 DOI:10.1007/s11172-024-4282-y

I. V. Loginova, I. Yu. Chukicheva, I. V. Fedorova, A. V. Kuchin

引用次数: 0

摘要

以 VO(acac)2 为催化剂，研究了一系列烷基酚（烷基为甲基和/或异冰片烷基）与二氧化氯的氧化反应。在 VO(acac)2 的存在下，对醌类化合物的选择性增加，氧化氯化产物的产量显著降低。

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Oxidation of substituted phenols with the ClO2—VO(acac)2 system

The oxidation of a series of alkylphenols (alkyl is methyl and/or isobornyl) with chlorine dioxide using the VO(acac)₂ as the catalyst was studied. In the presence of VO(acac)₂, the selectivity to quinones increases and the yield of oxidative chlorination products decreases significantly.

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.