1,2,3,4-萘和蒽二亚胺的合成与表征

IF 2.2 4区化学 Q2 CHEMISTRY, ORGANIC

Beilstein Journal of Organic Chemistry Pub Date : 2024-07-25 DOI:10.3762/bjoc.20.155

Adam D. Bass, Daniela Castellanos, Xavier A. Calicdan, Dennis D. Cao

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引用次数: 0

摘要

摘要我们报告了以环状亚胺为端盖的萘和蒽支架的合成和表征。通过 X 射线晶体学确定的 N-苯基衍生物的固态结构显示，根据核心中芳香环的数量，其堆积偏好发生了变化。标题化合物的光学和电子学性质与之前描述的其他异构体相比更胜一筹，并扩大了有机材料化学家可用的缺电子芳香化合物工具箱。Chem.2024, 20, 1767–1772. doi:10.3762/bjoc.20.155

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Synthesis and characterization of 1,2,3,4-naphthalene and anthracene diimides

Abstract

We report the synthesis and characterization of naphthalene and anthracene scaffolds end-capped by cyclic imides. The solid-state structures of the N-phenyl derivatives, determined by X-ray crystallography, reveal changes in packing preference based on the number of aromatic rings in the core. The optical and electronic properties of the title compounds compare favorably with other previously described isomers and expand the toolbox of electron-deficient aromatic compounds available to organic materials chemists.

Beilstein J. Org. Chem. 2024, 20, 1767–1772. doi:10.3762/bjoc.20.155

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来源期刊

Beilstein Journal of Organic Chemistry 化学-有机化学

CiteScore

4.90

自引率

3.70%

发文量

167

审稿时长

1.4 months

期刊介绍： The Beilstein Journal of Organic Chemistry is an international, peer-reviewed, Open Access journal. It provides a unique platform for rapid publication without any charges (free for author and reader) – Platinum Open Access. The content is freely accessible 365 days a year to any user worldwide. Articles are available online immediately upon publication and are publicly archived in all major repositories. In addition, it provides a platform for publishing thematic issues (theme-based collections of articles) on topical issues in organic chemistry. The journal publishes high quality research and reviews in all areas of organic chemistry, including organic synthesis, organic reactions, natural product chemistry, structural investigations, supramolecular chemistry and chemical biology.