Hikaru Okubo, Kento Hase, Ken Tamamoto, Yoshinobu Tsujii, Ken Nakano
{"title":"切向加载下冰-粘附界面的原位观测:亲水性 PPEGMA 聚合物刷的抗冰机制","authors":"Hikaru Okubo, Kento Hase, Ken Tamamoto, Yoshinobu Tsujii, Ken Nakano","doi":"10.1007/s11249-024-01886-w","DOIUrl":null,"url":null,"abstract":"<div><p>Techniques preventing icing and ice accumulation on surfaces are required to solve snow- and ice-induced accidents and disasters. Recently, hydrophilic polymers have attracted attention as a passive anti-icing method. This study examined the ice-adhesion properties of the hydrophilic poly[poly(ethylene glycol) methyl ether methacrylate] (PPEGMA) concentrated polymer brush (CPB). A custom-built apparatus was developed to obtain the ice-adhesion strength and visualize the dynamics of the ice-adhesion interface under tangential loading. The ice-adhesion interface for a PPEGMA-CPB-coated glass substrate was investigated by comparing it with the bare glass substrate. As a result, the CPB exhibited a low ice-adhesion strength of less than 100 kPa, the dependencies of which on the drive speed and temperature indicate a high-viscous liquid-like layer at the interface, even below the melting point of water, leading to the smooth onset of sliding due to its self-lubricity without any rupture events (including precursory events) observed for the bare glass.</p></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":null,"pages":null},"PeriodicalIF":2.9000,"publicationDate":"2024-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11249-024-01886-w.pdf","citationCount":"0","resultStr":"{\"title\":\"In-Situ Observation of Ice-Adhesion Interface Under Tangential Loading: Anti-Icing Mechanism of Hydrophilic PPEGMA Polymer Brush\",\"authors\":\"Hikaru Okubo, Kento Hase, Ken Tamamoto, Yoshinobu Tsujii, Ken Nakano\",\"doi\":\"10.1007/s11249-024-01886-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Techniques preventing icing and ice accumulation on surfaces are required to solve snow- and ice-induced accidents and disasters. Recently, hydrophilic polymers have attracted attention as a passive anti-icing method. This study examined the ice-adhesion properties of the hydrophilic poly[poly(ethylene glycol) methyl ether methacrylate] (PPEGMA) concentrated polymer brush (CPB). A custom-built apparatus was developed to obtain the ice-adhesion strength and visualize the dynamics of the ice-adhesion interface under tangential loading. The ice-adhesion interface for a PPEGMA-CPB-coated glass substrate was investigated by comparing it with the bare glass substrate. As a result, the CPB exhibited a low ice-adhesion strength of less than 100 kPa, the dependencies of which on the drive speed and temperature indicate a high-viscous liquid-like layer at the interface, even below the melting point of water, leading to the smooth onset of sliding due to its self-lubricity without any rupture events (including precursory events) observed for the bare glass.</p></div>\",\"PeriodicalId\":806,\"journal\":{\"name\":\"Tribology Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2024-07-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s11249-024-01886-w.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Tribology Letters\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11249-024-01886-w\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tribology Letters","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11249-024-01886-w","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
In-Situ Observation of Ice-Adhesion Interface Under Tangential Loading: Anti-Icing Mechanism of Hydrophilic PPEGMA Polymer Brush
Techniques preventing icing and ice accumulation on surfaces are required to solve snow- and ice-induced accidents and disasters. Recently, hydrophilic polymers have attracted attention as a passive anti-icing method. This study examined the ice-adhesion properties of the hydrophilic poly[poly(ethylene glycol) methyl ether methacrylate] (PPEGMA) concentrated polymer brush (CPB). A custom-built apparatus was developed to obtain the ice-adhesion strength and visualize the dynamics of the ice-adhesion interface under tangential loading. The ice-adhesion interface for a PPEGMA-CPB-coated glass substrate was investigated by comparing it with the bare glass substrate. As a result, the CPB exhibited a low ice-adhesion strength of less than 100 kPa, the dependencies of which on the drive speed and temperature indicate a high-viscous liquid-like layer at the interface, even below the melting point of water, leading to the smooth onset of sliding due to its self-lubricity without any rupture events (including precursory events) observed for the bare glass.
期刊介绍:
Tribology Letters is devoted to the development of the science of tribology and its applications, particularly focusing on publishing high-quality papers at the forefront of tribological science and that address the fundamentals of friction, lubrication, wear, or adhesion. The journal facilitates communication and exchange of seminal ideas among thousands of practitioners who are engaged worldwide in the pursuit of tribology-based science and technology.