Co(II)与 E-2-(((4-碘苯基)氨基)甲基)苯酚的混合配体氯化物配合物：晶体结构和固体中卤素键合的特征

IF 1.2 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Structural Chemistry Pub Date : 2024-07-26 DOI:10.1134/S0022476624070126

S. A. Adonin, P. A. Abramov, A. S. Zaguzin, A. S. Novikov

引用次数: 0

摘要

摘要通过氯化钴（II）与 E-(((4-碘苯基)亚氨基)甲基)苯酚（L）反应得到中性络合物 [L2CoCl2]，并通过单晶 X 射线衍射对其结构进行了研究。该结构包含 I⋯Cl 卤素键，其能量是通过量子化学计算估算的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Mixed-Ligand Chloride Complex of Co(II) withE-2-(((4-Iodophenyl)Imino)Methyl)Phenol: Crystal Structure and Features of Halogen Bonding in a Solid

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Mixed-Ligand Chloride Complex of Co(II) withE-2-(((4-Iodophenyl)Imino)Methyl)Phenol: Crystal Structure and Features of Halogen Bonding in a Solid

Neutral complex [L₂CoCl₂] is obtained by the reaction of cobalt(II) chloride with E-(((4-iodophenyl)imino)methyl)phenol (L), and its structure is studied by single crystal X-ray diffraction. The structure contains I⋯Cl halogen bonds whose energies are estimated by quantum chemical calculations.

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来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.