Co(II)与 E-2-(((4-碘苯基)氨基)甲基)苯酚的混合配体氯化物配合物：晶体结构和固体中卤素键合的特征

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-07-26 DOI:10.1134/S0022476624070126

S. A. Adonin, P. A. Abramov, A. S. Zaguzin, A. S. Novikov

引用次数: 0

摘要

摘要通过氯化钴（II）与 E-(((4-碘苯基)亚氨基)甲基)苯酚（L）反应得到中性络合物 [L2CoCl2]，并通过单晶 X 射线衍射对其结构进行了研究。该结构包含 I⋯Cl 卤素键，其能量是通过量子化学计算估算的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Mixed-Ligand Chloride Complex of Co(II) withE-2-(((4-Iodophenyl)Imino)Methyl)Phenol: Crystal Structure and Features of Halogen Bonding in a Solid

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Mixed-Ligand Chloride Complex of Co(II) withE-2-(((4-Iodophenyl)Imino)Methyl)Phenol: Crystal Structure and Features of Halogen Bonding in a Solid

Neutral complex [L₂CoCl₂] is obtained by the reaction of cobalt(II) chloride with E-(((4-iodophenyl)imino)methyl)phenol (L), and its structure is studied by single crystal X-ray diffraction. The structure contains I⋯Cl halogen bonds whose energies are estimated by quantum chemical calculations.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.