Lingjing Jiang, Dengqi Wu, Zishan Huang, Fengfeng Chen, Kai Chen, Aziz Bakhtiyarovich Ibragimov, Junkuo Gao
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In Situ Pyrolysis of ZIF-67 to Construct Co2N0.67@ZIF-67 for Photocatalytic CO2 Cycloaddition Reaction.
The development of heterogeneous catalysts with abundant active sites is pivotal for enhancing the efficiency of photothermal CO2 conversion. Herein, we report the construction of Co2N0.67@ZIF-67 through the in situ pyrolysis of ZIF-67 under low-temperature pyrolysis conditions. During the pyrolysis process, the crystal structure of ZIF-67 is predominantly preserved concurrently with the formation of Co2N0.67 nanoparticles (NPs) within the ZIF-67 pores. The optimal catalyst Co2N0.67@ZIF-67(450,2) not only possesses high photothermal efficiency but also can efficiently activate CO2. Benefiting from these characteristics, Co2N0.67@ZIF-67(450,2) exhibited significant catalytic activity in the photocatalytic cycloaddition of CO2 and epichlorohydrin. The yield of (chloromethyl)ethylene carbonate reached 95%, which is more than 4 times higher than that of ZIF-67 under visible light irradiation (300 W·m2 Xe lamp, 3 h). This study could offer an alternative approach to enhance the photocatalytic activity of MOFs through low-temperature pyrolysis.
期刊介绍：
Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.
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