超声波处理对高蜡原油及其沉淀物的性质和成分的影响

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-07-19 DOI:10.1134/S0965544124020026

G. I. Volkova, D. A. Zubarev, P. B. Kadychagov

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引用次数: 0

摘要

摘要用超声波（样品重量 50 g，频率 22 kHz，场强 8 W/cm2）处理高蜡原油 10 分钟。超声波处理导致原油粘度、粘流活化能、分散体系断裂比能、凝结点、倾点和沉淀量增加，沉淀结构也发生了变化。通过红外光谱和色谱-质谱法分析了原油、沉淀物和沥青质的油组分。经超声波处理的原油沉淀物油中的高分子量正构烷烃含量大大降低。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Effect of Ultrasonic Treatment on the Properties and Composition of High-Wax Crude Oil and Its Precipitates

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Effect of Ultrasonic Treatment on the Properties and Composition of High-Wax Crude Oil and Its Precipitates

High-wax crude oil was treated with ultrasound (sample weight 50 g, frequency 22 kHz, field intensity 8 W/cm²) for 10 min. The ultrasonic treatment led to an increase in the crude oil viscosity, viscous flow activation energy, specific energy of the break of the disperse system, congealing point, pour point, and precipitate amount and to changes in the precipitate structure. The oil fraction of the crude oil, precipitates, and raffinates was analyzed by IR spectroscopy and chromatography–mass spectrometry. The content of high-molecular-mass n-alkanes in oils from the precipitate of the ultrasonically treated crude oil considerably decreases.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.