S. A. Bushmin, Y. A. Vapnik, M. V. Ivanov, A. B. Kol’tsov, Y. M. Lebedeva, O. V. Aleksandrovich, E. V. Savva
{"title":"中地壳 P-T 条件下变质岩变质蜕变过程中流体的性质:以芬诺斯堪地盾贝洛莫利亚-拉普兰造山带博尔希-凯维地区为例","authors":"S. A. Bushmin, Y. A. Vapnik, M. V. Ivanov, A. B. Kol’tsov, Y. M. Lebedeva, O. V. Aleksandrovich, E. V. Savva","doi":"10.1134/S0869591124700097","DOIUrl":null,"url":null,"abstract":"<p>Properties of fluids under <i>P–T</i> conditions of the middle crust were studied with reference to the metasomatic alteration of metamorphic rocks (amphibolite facies) of the Bolshie Keivy nappe of the Keivy terrane of the Belomorian–Lapland collision orogen of the Fennoscandian shield. Properties of the fluids were studied in five selected types of rocks: metamorphic schists and gneisses with graphite, metasomatic quartz rocks with a high content of graphite, kyanite–quartz veins with wall-rock metasomatites, and metasomatic quartz-bearing kyanite rocks and anchimonomineral quartz veins. NaCl, CaCl<sub>2</sub>, CO<sub>2</sub>, N<sub>2</sub>, CH<sub>4,</sub> heavier hydrocarbons, and graphite were identified in the fluid inclusions using microthermometry and Raman spectroscopy. Using the method of multiequilibrium thermobarometry for mineral associations and the density of CO<sub>2</sub> inclusions, a retrograde <i>P–T</i> path was calculated, which reflects the <i>P–T</i> exhumation history of the rocks. An explanation was proposed for the presence of water inclusions with NaCl of low salinity among inclusions of high salinity with NaCl and CaCl<sub>2</sub>. Comparison of data on the H<sub>2</sub>O activity (inferred from mineral equilibria) and salt content (data on fluid inclusions) with those of a model fluid (thermodynamic model of the H<sub>2</sub>O–NaCl–CaCl<sub>2</sub>–CO<sub>2</sub> system) showed a good agreement between natural and model data. Natural and model data were synthesized to analyze variations in the phase state and chemical composition, fluid properties, including H<sub>2</sub>O activity, density, and salinity along the retrograde <i>P–T</i> trend.</p>","PeriodicalId":20026,"journal":{"name":"Petrology","volume":"32 4","pages":"478 - 501"},"PeriodicalIF":1.0000,"publicationDate":"2024-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Properties of Fluids during Metasomatic Alteration of Metamorphic Rocks under P–T Conditions of the Middle Crust: An Example from the Bolshie Keivy Region, Belomorian–Lapland Orogen, Fennoscandian Shield\",\"authors\":\"S. A. Bushmin, Y. A. Vapnik, M. V. Ivanov, A. B. Kol’tsov, Y. M. Lebedeva, O. V. Aleksandrovich, E. V. Savva\",\"doi\":\"10.1134/S0869591124700097\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Properties of fluids under <i>P–T</i> conditions of the middle crust were studied with reference to the metasomatic alteration of metamorphic rocks (amphibolite facies) of the Bolshie Keivy nappe of the Keivy terrane of the Belomorian–Lapland collision orogen of the Fennoscandian shield. Properties of the fluids were studied in five selected types of rocks: metamorphic schists and gneisses with graphite, metasomatic quartz rocks with a high content of graphite, kyanite–quartz veins with wall-rock metasomatites, and metasomatic quartz-bearing kyanite rocks and anchimonomineral quartz veins. NaCl, CaCl<sub>2</sub>, CO<sub>2</sub>, N<sub>2</sub>, CH<sub>4,</sub> heavier hydrocarbons, and graphite were identified in the fluid inclusions using microthermometry and Raman spectroscopy. Using the method of multiequilibrium thermobarometry for mineral associations and the density of CO<sub>2</sub> inclusions, a retrograde <i>P–T</i> path was calculated, which reflects the <i>P–T</i> exhumation history of the rocks. An explanation was proposed for the presence of water inclusions with NaCl of low salinity among inclusions of high salinity with NaCl and CaCl<sub>2</sub>. Comparison of data on the H<sub>2</sub>O activity (inferred from mineral equilibria) and salt content (data on fluid inclusions) with those of a model fluid (thermodynamic model of the H<sub>2</sub>O–NaCl–CaCl<sub>2</sub>–CO<sub>2</sub> system) showed a good agreement between natural and model data. Natural and model data were synthesized to analyze variations in the phase state and chemical composition, fluid properties, including H<sub>2</sub>O activity, density, and salinity along the retrograde <i>P–T</i> trend.</p>\",\"PeriodicalId\":20026,\"journal\":{\"name\":\"Petrology\",\"volume\":\"32 4\",\"pages\":\"478 - 501\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2024-07-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Petrology\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0869591124700097\",\"RegionNum\":4,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Petrology","FirstCategoryId":"89","ListUrlMain":"https://link.springer.com/article/10.1134/S0869591124700097","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Properties of Fluids during Metasomatic Alteration of Metamorphic Rocks under P–T Conditions of the Middle Crust: An Example from the Bolshie Keivy Region, Belomorian–Lapland Orogen, Fennoscandian Shield
Properties of fluids under P–T conditions of the middle crust were studied with reference to the metasomatic alteration of metamorphic rocks (amphibolite facies) of the Bolshie Keivy nappe of the Keivy terrane of the Belomorian–Lapland collision orogen of the Fennoscandian shield. Properties of the fluids were studied in five selected types of rocks: metamorphic schists and gneisses with graphite, metasomatic quartz rocks with a high content of graphite, kyanite–quartz veins with wall-rock metasomatites, and metasomatic quartz-bearing kyanite rocks and anchimonomineral quartz veins. NaCl, CaCl2, CO2, N2, CH4, heavier hydrocarbons, and graphite were identified in the fluid inclusions using microthermometry and Raman spectroscopy. Using the method of multiequilibrium thermobarometry for mineral associations and the density of CO2 inclusions, a retrograde P–T path was calculated, which reflects the P–T exhumation history of the rocks. An explanation was proposed for the presence of water inclusions with NaCl of low salinity among inclusions of high salinity with NaCl and CaCl2. Comparison of data on the H2O activity (inferred from mineral equilibria) and salt content (data on fluid inclusions) with those of a model fluid (thermodynamic model of the H2O–NaCl–CaCl2–CO2 system) showed a good agreement between natural and model data. Natural and model data were synthesized to analyze variations in the phase state and chemical composition, fluid properties, including H2O activity, density, and salinity along the retrograde P–T trend.
期刊介绍:
Petrology is a journal of magmatic, metamorphic, and experimental petrology, mineralogy, and geochemistry. The journal offers comprehensive information on all multidisciplinary aspects of theoretical, experimental, and applied petrology. By giving special consideration to studies on the petrography of different regions of the former Soviet Union, Petrology provides readers with a unique opportunity to refine their understanding of the geology of the vast territory of the Eurasian continent. The journal welcomes manuscripts from all countries in the English or Russian language.