Felipe Arretche , Eliton P. Seidel , Wagner Tenfen
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In particular, we show that the Hara and the semiclassical exchange potentials are able to reproduce reference low energy phase shifts through a simple scale transformation, in opposition to the previous approaches where energy dependent corrections to the local momentum were adopted. We provide the scale factors and phase shifts for electron scattering by He, Ne and Ar atoms for <span><math><mrow><mi>k</mi><mo><</mo></mrow></math></span> 1,0 a<span><math><msubsup><mrow></mrow><mrow><mn>0</mn></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msubsup></math></span>. Such scaling factors can be determined reproducing the scattering length and the number of s-wave bound states from exact exchange calculations. We also show that the scaling procedure works for electronic densities that present the physically correct asymptotic behavior. The present results are important to the research field, since they form the basis to construction of scattering models based on optical potential approaches.</p></div>","PeriodicalId":15726,"journal":{"name":"Journal of Electron Spectroscopy and Related Phenomena","volume":"274 ","pages":"Article 147460"},"PeriodicalIF":1.8000,"publicationDate":"2024-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Scale transformations in model exchange potentials in low energy electron-atom scattering\",\"authors\":\"Felipe Arretche , Eliton P. Seidel , Wagner Tenfen\",\"doi\":\"10.1016/j.elspec.2024.147460\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Model exchange potentials are particularly interesting to account for the indistinguishability between the projectile and target electrons in electron-atom scattering in vacuo and plasma environments. It is well known that their performance is pretty satisfactory in the high energies but also that discrepancies from the results obtained with exact exchange are found toward the zero energy limit. In this article, we examine how well established model exchange potentials based on the free electron gas approach compare to phase shifts calculated considering exchange in exact form. In particular, we show that the Hara and the semiclassical exchange potentials are able to reproduce reference low energy phase shifts through a simple scale transformation, in opposition to the previous approaches where energy dependent corrections to the local momentum were adopted. We provide the scale factors and phase shifts for electron scattering by He, Ne and Ar atoms for <span><math><mrow><mi>k</mi><mo><</mo></mrow></math></span> 1,0 a<span><math><msubsup><mrow></mrow><mrow><mn>0</mn></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msubsup></math></span>. Such scaling factors can be determined reproducing the scattering length and the number of s-wave bound states from exact exchange calculations. We also show that the scaling procedure works for electronic densities that present the physically correct asymptotic behavior. The present results are important to the research field, since they form the basis to construction of scattering models based on optical potential approaches.</p></div>\",\"PeriodicalId\":15726,\"journal\":{\"name\":\"Journal of Electron Spectroscopy and Related Phenomena\",\"volume\":\"274 \",\"pages\":\"Article 147460\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-07-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Electron Spectroscopy and Related Phenomena\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0368204824000434\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"SPECTROSCOPY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electron Spectroscopy and Related Phenomena","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0368204824000434","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
引用次数: 0
摘要
模型交换势对于解释在真空和等离子体环境下电子原子散射中射弹电子和目标电子之间的不可分性尤为重要。众所周知,模型交换势在高能量下的表现相当令人满意,但在零能量极限下,模型交换势与精确交换得到的结果也存在差异。在本文中,我们研究了基于自由电子气体方法的成熟模型交换势与精确交换计算出的相移的比较。特别是,我们表明哈拉和半经典交换势能够通过简单的尺度变换重现参考的低能相移,这与之前采用的对局部动量进行能量依赖修正的方法截然不同。我们提供了 k< 1,0 a0-1 时 He、Ne 和 Ar 原子电子散射的尺度因子和相移。这些比例因子可以通过精确交换计算再现散射长度和 s 波束缚态的数量来确定。我们还表明,缩放程序适用于呈现物理上正确渐近行为的电子密度。本研究成果对研究领域具有重要意义,因为它们为构建基于光学势方法的散射模型奠定了基础。
Scale transformations in model exchange potentials in low energy electron-atom scattering
Model exchange potentials are particularly interesting to account for the indistinguishability between the projectile and target electrons in electron-atom scattering in vacuo and plasma environments. It is well known that their performance is pretty satisfactory in the high energies but also that discrepancies from the results obtained with exact exchange are found toward the zero energy limit. In this article, we examine how well established model exchange potentials based on the free electron gas approach compare to phase shifts calculated considering exchange in exact form. In particular, we show that the Hara and the semiclassical exchange potentials are able to reproduce reference low energy phase shifts through a simple scale transformation, in opposition to the previous approaches where energy dependent corrections to the local momentum were adopted. We provide the scale factors and phase shifts for electron scattering by He, Ne and Ar atoms for 1,0 a. Such scaling factors can be determined reproducing the scattering length and the number of s-wave bound states from exact exchange calculations. We also show that the scaling procedure works for electronic densities that present the physically correct asymptotic behavior. The present results are important to the research field, since they form the basis to construction of scattering models based on optical potential approaches.
期刊介绍:
The Journal of Electron Spectroscopy and Related Phenomena publishes experimental, theoretical and applied work in the field of electron spectroscopy and electronic structure, involving techniques which use high energy photons (>10 eV) or electrons as probes or detected particles in the investigation.