电离能与水合能之间的相关性

IF 1.4 4区化学 Q4 CHEMISTRY, PHYSICAL

Journal of Solution Chemistry Pub Date : 2024-07-11 DOI:10.1007/s10953-024-01399-z

Andrew Das Arulsamy

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引用次数: 0

摘要

水合能的计算在物理、化学和生命科学中极为重要，因此，如果要利用这些能量推导出适当、正确的物理化学机制，就必须准确确定其数值。在这里，我们证明了过渡金属阳离子的电离能和水合能之间存在绝对相关性。上述绝对相关性可以明确地用于验证二价和三价过渡金属阳离子的水合能计算结果。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Correlation Between Ionization and Hydration Energies

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Correlation Between Ionization and Hydration Energies

Calculations of hydration energies are extremely important in physical, chemical, and life sciences, and therefore their values need to be accurately determined if these energies were to be used to derive the proper and correct physico-chemical mechanisms. Here, we prove the existence of absolute correlation between ionization and hydration energies for transition metal cations. The said absolute correlation can be exploited in an unambiguous manner to verify the calculated hydration energies for divalent and trivalent transition metal cations.

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来源期刊

Journal of Solution Chemistry 化学-物理化学

CiteScore

2.30

自引率

0.00%

发文量

审稿时长

3-8 weeks

期刊介绍： Journal of Solution Chemistry offers a forum for research on the physical chemistry of liquid solutions in such fields as physical chemistry, chemical physics, molecular biology, statistical mechanics, biochemistry, and biophysics. The emphasis is on papers in which the solvent plays a dominant rather than incidental role. Featured topics include experimental investigations of the dielectric, spectroscopic, thermodynamic, transport, or relaxation properties of both electrolytes and nonelectrolytes in liquid solutions.