普鲁士蓝类似物能否成为推动后锂电池发展的圣杯?

IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY
Mecaelah S. Palaganas, Jayson S. Garcia, Giancarlo Dominador D. Sanglay, Lora Monique E. Sapanta, Dr. Lawrence A. Limjuco, Prof. Joey D. Ocon
{"title":"普鲁士蓝类似物能否成为推动后锂电池发展的圣杯?","authors":"Mecaelah S. Palaganas,&nbsp;Jayson S. Garcia,&nbsp;Giancarlo Dominador D. Sanglay,&nbsp;Lora Monique E. Sapanta,&nbsp;Dr. Lawrence A. Limjuco,&nbsp;Prof. Joey D. Ocon","doi":"10.1002/batt.202400280","DOIUrl":null,"url":null,"abstract":"<p>The recent classification of lithium as a critical raw material surged the research and development (R&amp;D) of post-lithium batteries (PLBs). The larger cation charge carriers of these PLBs consequently entailed extensive materials R&amp;D for battery components, especially cathode. Prussian Blue (PB) and its analogues (PBAs) have emerged as promising cathode materials for PLBs due to their desirable characteristics, including a three-dimensional open framework structure that facilitates fast ion diffusion for both monovalent (Li<sup>+</sup>, Na<sup>+</sup>, K<sup>+</sup>) and multivalent (Mg<sup>2+</sup>, Ca<sup>2+</sup>, Zn<sup>2+</sup>, Al<sup>3+</sup>) ions, stable framework structures, electrochemical tunability, availability of widely used precursors, and ease of synthesis. Our comprehensive review reveals that several challenges are yet to be addressed in employing PBAs as cathode materials for PLBs, <i>viz</i>., vacancies, crystal water, side reactions, and conductivity issues. This review paper provides an exhaustive survey of material development, including the mitigation strategies of the challenges in employing PBAs as cathode materials for advancing PLBs (i. e., sodium-ion batteries (SIBs), potassium-ion batteries (KIBs), magnesium-ion batteries (MIBs), calcium-ion batteries (CIBs), zinc-ion batteries (ZIBs), aluminum-ion batteries (AIBs)) towards commercialization.</p>","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"7 10","pages":""},"PeriodicalIF":5.1000,"publicationDate":"2024-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Can Prussian Blue Analogues be Holy Grail for Advancing Post-Lithium Batteries?\",\"authors\":\"Mecaelah S. Palaganas,&nbsp;Jayson S. Garcia,&nbsp;Giancarlo Dominador D. Sanglay,&nbsp;Lora Monique E. Sapanta,&nbsp;Dr. Lawrence A. Limjuco,&nbsp;Prof. Joey D. Ocon\",\"doi\":\"10.1002/batt.202400280\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The recent classification of lithium as a critical raw material surged the research and development (R&amp;D) of post-lithium batteries (PLBs). The larger cation charge carriers of these PLBs consequently entailed extensive materials R&amp;D for battery components, especially cathode. Prussian Blue (PB) and its analogues (PBAs) have emerged as promising cathode materials for PLBs due to their desirable characteristics, including a three-dimensional open framework structure that facilitates fast ion diffusion for both monovalent (Li<sup>+</sup>, Na<sup>+</sup>, K<sup>+</sup>) and multivalent (Mg<sup>2+</sup>, Ca<sup>2+</sup>, Zn<sup>2+</sup>, Al<sup>3+</sup>) ions, stable framework structures, electrochemical tunability, availability of widely used precursors, and ease of synthesis. Our comprehensive review reveals that several challenges are yet to be addressed in employing PBAs as cathode materials for PLBs, <i>viz</i>., vacancies, crystal water, side reactions, and conductivity issues. This review paper provides an exhaustive survey of material development, including the mitigation strategies of the challenges in employing PBAs as cathode materials for advancing PLBs (i. e., sodium-ion batteries (SIBs), potassium-ion batteries (KIBs), magnesium-ion batteries (MIBs), calcium-ion batteries (CIBs), zinc-ion batteries (ZIBs), aluminum-ion batteries (AIBs)) towards commercialization.</p>\",\"PeriodicalId\":132,\"journal\":{\"name\":\"Batteries & Supercaps\",\"volume\":\"7 10\",\"pages\":\"\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-07-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Batteries & Supercaps\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/batt.202400280\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Batteries & Supercaps","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/batt.202400280","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0

摘要

最近,锂被列为一种重要的原材料,从而推动了后锂电池(PLB)的研发工作。这些 PLB 的阳离子电荷载体较大,因此需要对电池组件,尤其是阴极进行大量的材料研发。普鲁士蓝(PB)及其类似物(PBAs)因其理想的特性,包括三维开放式框架结构有利于单价(Li+、Na+、K+)和多价(Mg2+、Ca2+、Zn2+、Al3+)离子的快速扩散、稳定的框架结构、电化学可调性、可获得广泛使用的前驱体以及易于合成等,已成为有前途的 PLB 阴极材料。我们的综合综述显示,将 PBAs 用作 PLB 的阴极材料还有几个难题有待解决,即 PBAs 中的电化学不活泼成分导致的空位、结晶水、副反应和导电性问题。本综述论文对材料开发进行了详尽的调查,包括采用 PBA 作为推进 PLB 的阴极材料所面临挑战的缓解策略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Can Prussian Blue Analogues be Holy Grail for Advancing Post-Lithium Batteries?

Can Prussian Blue Analogues be Holy Grail for Advancing Post-Lithium Batteries?

The recent classification of lithium as a critical raw material surged the research and development (R&D) of post-lithium batteries (PLBs). The larger cation charge carriers of these PLBs consequently entailed extensive materials R&D for battery components, especially cathode. Prussian Blue (PB) and its analogues (PBAs) have emerged as promising cathode materials for PLBs due to their desirable characteristics, including a three-dimensional open framework structure that facilitates fast ion diffusion for both monovalent (Li+, Na+, K+) and multivalent (Mg2+, Ca2+, Zn2+, Al3+) ions, stable framework structures, electrochemical tunability, availability of widely used precursors, and ease of synthesis. Our comprehensive review reveals that several challenges are yet to be addressed in employing PBAs as cathode materials for PLBs, viz., vacancies, crystal water, side reactions, and conductivity issues. This review paper provides an exhaustive survey of material development, including the mitigation strategies of the challenges in employing PBAs as cathode materials for advancing PLBs (i. e., sodium-ion batteries (SIBs), potassium-ion batteries (KIBs), magnesium-ion batteries (MIBs), calcium-ion batteries (CIBs), zinc-ion batteries (ZIBs), aluminum-ion batteries (AIBs)) towards commercialization.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
8.60
自引率
5.30%
发文量
223
期刊介绍: Electrochemical energy storage devices play a transformative role in our societies. They have allowed the emergence of portable electronics devices, have triggered the resurgence of electric transportation and constitute key components in smart power grids. Batteries & Supercaps publishes international high-impact experimental and theoretical research on the fundamentals and applications of electrochemical energy storage. We support the scientific community to advance energy efficiency and sustainability.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信